Propanenitrile, 3-(dichloromethylsilyl)-

Base Information

• Chemical Name: Propanenitrile, 3-(dichloromethylsilyl)-
• CAS No.: 1071-21-2
• Molecular Formula: C4H7Cl2NSi
• Molecular Weight: 168.098
• Hs Code.: 2931900090
• European Community (EC) Number: 213-985-9
• DSSTox Substance ID: DTXSID40910235
• Nikkaji Number: J21.113C
• Wikidata: Q82880005
• Mol file: 1071-21-2.mol

Synonyms:1071-21-2;2-CYANOETHYLMETHYLDICHLOROSILANE;3-[Dichloro(methyl)silyl]propanenitrile;Propanenitrile, 3-(dichloromethylsilyl)-;Dichloro(2-cyanoethyl)methylsilane;Propanenitrile,3-(dichloromethylsilyl)-;Silane, dichloromethyl (2-cyanoethyl)-;EINECS 213-985-9;3-(dichloro(methyl)silyl)propanenitrile;C4H7Cl2NSi;C4-H7-Cl2-N-Si;SCHEMBL2101321;DTXSID40910235;(2-Cyanoethyl)methyldichlorosilane;Methyl(2-cyanoethyl)dichlorosilane;MFCD00013819;AKOS006343691;3-[Dichloro(methyl)silyl]propanenitrile #;3-(DICHLOROMETHYLSILYL)-PROPIONITRILE;FT-0633283;S04825

Chemical Property of Propanenitrile, 3-(dichloromethylsilyl)-

Chemical Property:

• Vapor Pressure: 0.257mmHg at 25°C
• Melting Point: <0°C
• Refractive Index: 1.4550
• Boiling Point: 204.9 °C at 760 mmHg
• Flash Point: 77.7 °C
• PSA: 23.79000
• Density: 1.147 g/cm³
• LogP: 2.44968
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 166.9724811
• Heavy Atom Count: 8
• Complexity: 115

Purity/Quality:

98% ^*data from raw suppliers

2-CYANOETHYLMETHYLDICHLOROSILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22-34
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](CCC#N)(Cl)Cl

Technology Process of Propanenitrile, 3-(dichloromethylsilyl)-

There total 8 articles about Propanenitrile, 3-(dichloromethylsilyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.6%

3-Chloropropionitrile (542-76-7) + Methyltrichlorosilane (75-79-6) → dichloro(2-cyanoethyl)methylsilane (1071-21-2)

Guidance literature:

With magnesium; ethylene dibromide; manganese(ll) chloride; In tetrahydrofuran; at 50 ℃; for 2h; Inert atmosphere;

Reference yield: 95.7%

Dichloromethylsilane (75-54-7) + acrylonitrile (107-13-1,25014-41-9) → dichloro(2-cyanoethyl)methylsilane (1071-21-2)

Guidance literature:

With dihydrogen hexachloroplatinate; chloro-trimethyl-silane; Methyltrichlorosilane; tetrachlorosilane; at 90 ℃; for 2h; under 15001.5 Torr; Large scale;

Reference yield:

dimethylmonochlorosilane (1066-35-9) + acrylonitrile (107-13-1,25014-41-9) → dichloro(2-cyanoethyl)methylsilane (1071-21-2)

Guidance literature:

With copper(I) oxide; N,N,N,N,-tetramethylethylenediamine; at 60 ℃; Reflux;

upstream raw materials:

pyridine

Dichloromethylsilane

acrylonitrile

acetonitrile

Downstream raw materials:

3-(Methyl-bis-octyloxy-silanyl)-propionitrile

3-(Bis-hexyloxy-methyl-silanyl)-propionitrile

diethoxy[2-(ethoxycarbonyl)ethyl](methyl)silane

tributyltin chloride

Refernces

• 1、 McCann,zit. bei Dyer,Lee. "". . p. 1985. Retrieved 1968.
• 2、 Bluestein. "". . p. 1000. Retrieved 1961.
• 3、 -. "Synthesis method of cyano-containing organosilicon compound". Paragraph 0051-0053. . Retrieved 2019/07/01.
• 4、 -. "FUNCTIONALIZED SILANES AND ELECTROLYTE COMPOSITIONS AND ELECTROCHEMICAL DEVICES CONTAINING THEM". Page/Page column 33; 34. . Retrieved 2016/04/26.