Methyl 2-methyl-3-oxopropanoate

Base Information

Chemical Name:Methyl 2-methyl-3-oxopropanoate
CAS No.:51673-64-4
Deprecated CAS:117585-17-8
Molecular Formula:C5H8 O3
Molecular Weight:116.117
Hs Code.:2918300090
European Community (EC) Number:257-343-6
DSSTox Substance ID:DTXSID10885966
Nikkaji Number:J38.918H
Mol file:51673-64-4.mol

Synonyms:methyl 2-methyl-3-oxopropanoate;51673-64-4;Methyl 3-oxoisobutyrate;2-Formylpropionic acid, methyl ester;Propanoic acid, 2-methyl-3-oxo-, methyl ester;EINECS 257-343-6;methyl alpha-formylpropionate;Methyl 2-methyl-3-oxopropionate;alpha-formylpropionic acid methyl ester;methyl 2-formylpropionate;Methyl 2-Formylpropanoate;SCHEMBL222114;Methyl2-Methyl-3-oxopropanoate;DTXSID10885966;2-Formylpropanoic acid methyl ester;AC6281;MFCD00044011;AKOS006273779;alpha-formyl-propionic acid methyl ester;SY238219;2-Methyl-3-oxopropanoic acid methyl ester;2-methyl-3-oxo-propionic acid methyl ester;FT-0713873;EN300-6970235;W-111024

Suppliers and Price of Methyl 2-methyl-3-oxopropanoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Methyl2-Formylpropanoate
1g
$ 1320.00

Medical Isotopes, Inc.
Methyl2-Formylpropanoate
100 mg
$ 650.00

American Custom Chemicals Corporation
METHYL-2-METHYL-3-OXOPROPANOATE 95.00%
5MG
$ 505.20

Alichem
Methyl2-methyl-3-oxopropanoate
1g
$ 2800.00

Alichem
Methyl2-methyl-3-oxopropanoate
100mg
$ 350.00

Total 14 raw suppliers

Chemical Property of Methyl 2-methyl-3-oxopropanoate

Chemical Property:

Vapor Pressure:6.15mmHg at 25°C
Boiling Point:140.4°C at 760 mmHg
PKA:8.13±0.29(Predicted)
Flash Point:43.6°C
PSA：43.37000
Density:1.034g/cm³
LogP:-0.00560
XLogP3:0.3
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:116.047344113
Heavy Atom Count:8
Complexity:97.8

Purity/Quality:

97% ^*data from raw suppliers

Methyl2-Formylpropanoate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C=O)C(=O)OC

Technology Process of Methyl 2-methyl-3-oxopropanoate

There total 26 articles about Methyl 2-methyl-3-oxopropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 76526-43-7
methyl 3,3-dimethoxy-2-methylpropionate

: 51673-64-4
methyl 2-methyl-3-oxopropanoate

Guidance literature:: With sulfuric acid; silica gel; In dichloromethane; water;

Reference yield: 68.0%

: 201230-82-2
carbon monoxide

: 292638-85-8,9003-21-8,96-33-3
acrylic acid methyl ester

: 13865-19-5
4-oxobutanoic acid methyl ester

: 51673-64-4
methyl 2-methyl-3-oxopropanoate

Guidance literature:: With hydrogen; Rh(1+)(1,5-cyclooctadiene)(η6-C6H5B(1-)Ph3); 1,4-di(diphenylphosphino)-butane; In dichloromethane; at 80 ℃; for 18h; under 31028.9 Torr; Yields of byproduct given;
DOI:10.1021/jo00108a007

Reference yield: 49.0%

: 107-31-3
Methyl formate

: 554-12-1
propanoic acid methyl ester

: 51673-64-4
methyl 2-methyl-3-oxopropanoate

Guidance literature:: Methyl formate; propanoic acid methyl ester; With titanium tetrachloride; triethylamine; In dichloromethane; at 0 - 25 ℃; Inert atmosphere;

With water; In dichloromethane;
DOI:10.1021/ol9013359