Hydrazine,1,2-dimethyl-1-phenyl-

Base Information

• Chemical Name: Hydrazine,1,2-dimethyl-1-phenyl-
• CAS No.: 29195-01-5
• Molecular Formula: C8H12 N2
• Molecular Weight: 136.197
• European Community (EC) Number: 249-500-2
• DSSTox Substance ID: DTXSID30183456
• Nikkaji Number: J250.792G
• Wikidata: Q83054247
• Mol file: 29195-01-5.mol

Synonyms:1,2-Dimethyl-1-phenylhydrazine;1,2-Dimethylphenylhydrazine; N,N'-Dimethyl-N-phenylhydrazine

Chemical Property of Hydrazine,1,2-dimethyl-1-phenyl-

Chemical Property:

• Boiling Point: 188.6oC at 760 mmHg
• Flash Point: 71.3oC
• Density: 0.999g/cm3
• XLogP3: 2.1
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 136.100048391
• Heavy Atom Count: 10
• Complexity: 87.3

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CNN(C)C1=CC=CC=C1

Technology Process of Hydrazine,1,2-dimethyl-1-phenyl-

There total 13 articles about Hydrazine,1,2-dimethyl-1-phenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

1-Methyl-1-phenylhydrazine (618-40-6) + methyl iodide (74-88-4) → N'-methyl-N-methyl-N-phenylhydrazine (29195-01-5)

Guidance literature:

1-Methyl-1-phenylhydrazine; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Inert atmosphere;

methyl iodide; In tetrahydrofuran; at 0 ℃; Inert atmosphere;

DOI:10.1055/s-0030-1260082

Reference yield: 78.0%

methyllithium (917-54-4) + (Z)-(tert-butylsulfanyl)(phenyl)diazene (52144-59-9) → N'-methyl-N-methyl-N-phenylhydrazine (29195-01-5) + N-methylaniline (100-61-8)

Guidance literature:

In diethyl ether; at 0 - 25 ℃; for 0.416667h;

DOI:10.1055/s-2003-38082

Reference yield: 58.0%

propionic acid N.N'-dimethyl-N'-phenylhydrazide (38435-93-7) → N'-methyl-N-methyl-N-phenylhydrazine (29195-01-5)

Guidance literature:

With hydrogenchloride; In water; at 40 ℃; for 48h;

DOI:10.1016/j.tetlet.2009.02.060

upstream raw materials:

formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)

N'-methyl-N'-phenylformohydrazide

methyl iodide

hydrogenchloride

Downstream raw materials:

N¹,N²-Dimethyl-N²-phenylformohydrazidphenylsulfonylimid

propionic acid N_.N'-dimethyl-N'-phenylhydrazide

C₁₀H₁₁⁽²⁾H₃N₂O

formic acid-(N,N'-dimethyl-N'-phenyl-hydrazide)