PhI(Phth)

Base Information

• Chemical Name: PhI(Phth)
• CAS No.: 57357-31-0
• Molecular Formula: C₁₄H₉IO₄
• Molecular Weight: 368.128
• Mol file: 57357-31-0.mol

Synonyms:PhI(Phth)

Chemical Property of PhI(Phth)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of PhI(Phth)

There total 2 articles about PhI(Phth) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

[bis(acetoxy)iodo]benzene (3240-34-4) + benzene-1,2-dicarboxylic acid (88-99-3,73607-73-5) → PhI(Phth) (57357-31-0)

Guidance literature:

In chlorobenzene; at 50 ℃; for 1h;

DOI:10.1021/acs.joc.8b01988

Reference yield:

Phthalic acid dibutyl ester (84-74-2) → PhI(Phth) (57357-31-0)

Guidance literature:

Multi-step reaction with 2 steps

1: potassium hydroxide / methanol / 1 h / 20 °C

2: chlorobenzene / 1 h / 50 °C

With potassium hydroxide; In methanol; chlorobenzene;

DOI:10.1021/acs.joc.8b01988

Reference yield: 77.0%

Allyl acetate (591-87-7) + carbon monoxide (201230-82-2) + diazomethyl-trimethyl-silane (18107-18-1) + PhI(Phth) (57357-31-0) → C16H18O8

Guidance literature:

Allyl acetate; carbon monoxide; PhI(Phth); With palladium diacetate; trifluoroborane diethyl ether; In toluene; acetonitrile; at 20 ℃; for 12h; under 760.051 Torr; Schlenk technique;

diazomethyl-trimethyl-silane; With methanol; In hexane; regioselective reaction; Schlenk technique;

DOI:10.1002/anie.201607248

upstream raw materials:

[bis(acetoxy)iodo]benzene

benzene-1,2-dicarboxylic acid

Phthalic acid dibutyl ester