tetraphenylporphyrine aluminum chloride

Base Information

• Chemical Name: tetraphenylporphyrine aluminum chloride
• CAS No.: 71102-37-9
• Molecular Formula: C₄₄H₂₈AlClN₄
• Molecular Weight: 675.168
• Mol file: 71102-37-9.mol

Synonyms:tetraphenylporphyrine aluminum chloride

Chemical Property of tetraphenylporphyrine aluminum chloride

Chemical Property:

Purity/Quality:

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Technology Process of tetraphenylporphyrine aluminum chloride

There total 5 articles about tetraphenylporphyrine aluminum chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

diethylaluminium chloride (96-10-6) + 5,15,10,20-tetraphenylporphyrin (917-23-7,20998-75-8) → (5,10,15,20-tetraphenylporphyrin)aluminum chloride (71102-37-9)

Guidance literature:

In dichloromethane; at 20 ℃; for 2h; Inert atmosphere;

DOI:10.1002/cjoc.201800019

Reference yield: 91.0%

aluminium trichloride (7446-70-0) + 5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) → (5,10,15,20-tetraphenylporphyrin)aluminum chloride (71102-37-9)

Guidance literature:

In benzonitrile; under Ar;

Reference yield: 85.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + diethylaluminium chloride (96-10-6) → (5,10,15,20-tetraphenylporphyrin)aluminum chloride (71102-37-9)

Guidance literature:

In hexane; dichloromethane; (N2); a soln. of Al compd. in hexane added slowly at room temp. to a soln. of ligand in CH2Cl2, stirred for 3 h; evapd. (vac.);

DOI:10.1021/ic048597x

upstream raw materials:

diethylaluminium chloride

5,15,10,20-tetraphenylporphyrin

benzaldehyde

aluminium trichloride

Downstream raw materials:

[Al(tetraphenylporphyrin)(OCH₂CH(CH₃)Cl)]

[5,10,15,20-tetra(phenyl)porphyrinato]aluminum(III) hydroxide