[(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

Base Information

Chemical Name:[(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane
CAS No.:954148-43-7
Molecular Formula:C₂₇H₄₅N₃O₂Si
Molecular Weight:471.759
Hs Code.:

Synonyms:[(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

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Chemical Property of [(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

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Technology Process of [(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

There total 10 articles about [(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 954148-42-6
3-((1R,6S)-6-benzyloxymethyl-1-(triisopropylsilanyloxy)methyl-cyclohex-3-enyl)-propan-1-ol

: 954148-43-7
[(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

Guidance literature:: With diphenylphosphoranyl azide; In tetrahydrofuran; at 20 ℃; for 5h;
DOI:10.1021/ol701772d

Reference yield:

: 954148-39-1
methyl (1R,6S)-6-(benzyloxymethyl)-1-(3-(4-methoxybenzyloxy)propyl)cyclohex-3-enecarboxylate

: 954148-43-7
[(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

Guidance literature:: Multi-step reaction with 4 steps

1: DIBAL-H / CH₂Cl₂ / -78 - -20 °C

2: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

3: 2,3-dichloro-5,6-dicyanobenzoquinone; H₂O / CH₂Cl₂ / 0.25 h / 20 °C

4: diphenylphosphoryl azide / tetrahydrofuran / 5 h / 20 °C

With 2,6-dimethylpyridine; diphenylphosphoranyl azide; water; diisobutylaluminium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; 4: Mitsunobu reaction;
DOI:10.1021/ol701772d

Reference yield:

: 954148-40-4
{(1R,6S)-6-(benzyloxymethyl)-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enyl}-methanol

: 954148-43-7
[(1R,6S)-1-(3-azido-propyl)-6-benzyloxymethyl-cyclohex-3-enylmethoxy]-triisopropyl-silane

Guidance literature:: Multi-step reaction with 3 steps

1: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

2: 2,3-dichloro-5,6-dicyanobenzoquinone; H₂O / CH₂Cl₂ / 0.25 h / 20 °C

3: diphenylphosphoryl azide / tetrahydrofuran / 5 h / 20 °C

With 2,6-dimethylpyridine; diphenylphosphoranyl azide; water; 2,3-dicyano-5,6-dichloro-p-benzoquinone; In tetrahydrofuran; dichloromethane; 3: Mitsunobu reaction;
DOI:10.1021/ol701772d