{(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

Base Information

Chemical Name:{(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane
CAS No.:954148-41-5
Molecular Formula:C₃₅H₅₄O₄Si
Molecular Weight:566.897
Hs Code.:

Synonyms:{(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

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Chemical Property of {(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

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Technology Process of {(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

There total 8 articles about {(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 954148-40-4
{(1R,6S)-6-(benzyloxymethyl)-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enyl}-methanol

: 80522-42-5
triisopropylsilyl trifluoromethanesulfonate

: 954148-41-5
{(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

Guidance literature:: With 2,6-dimethylpyridine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/ol701772d

Reference yield:

: 954148-39-1
methyl (1R,6S)-6-(benzyloxymethyl)-1-(3-(4-methoxybenzyloxy)propyl)cyclohex-3-enecarboxylate

: 954148-41-5
{(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

Guidance literature:: Multi-step reaction with 2 steps

1: DIBAL-H / CH₂Cl₂ / -78 - -20 °C

2: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

With 2,6-dimethylpyridine; diisobutylaluminium hydride; In dichloromethane;
DOI:10.1021/ol701772d

Reference yield:

: 954148-52-8
C₁₇H₂₂O₃

: 954148-41-5
{(1R,6S)-6-benzyloxymethyl-1-[3-(4-methoxy-benzyloxy)-propyl]-cyclohex-3-enylmethoxy}-triisopropyl-silane

Guidance literature:: Multi-step reaction with 6 steps

1.1: lithium hydroxide monohydrate / methanol; H₂O / 0 - 20 °C

2.1: Jones' reagent / acetone / 5 °C

3.1: acetyl chloride / 0 - 20 °C

4.1: LiHMDS / tetrahydrofuran / 2 h / -78 °C

4.2: tetrahydrofuran / -78 - 20 °C

5.1: DIBAL-H / CH₂Cl₂ / -78 - -20 °C

6.1: 2,6-lutidine / CH₂Cl₂ / 0 - 20 °C

With 2,6-dimethylpyridine; lithium hydroxide; jones' reagent; diisobutylaluminium hydride; acetyl chloride; lithium hexamethyldisilazane; In tetrahydrofuran; methanol; dichloromethane; water; acetone;
DOI:10.1021/ol701772d