Furfuryl methyl sulfide

Base Information

• Chemical Name: Furfuryl methyl sulfide
• CAS No.: 1438-91-1
• Molecular Formula: C6H8OS
• Molecular Weight: 128.195
• Hs Code.: 29321900
• European Community (EC) Number: 215-874-0
• UNII: LMB8355W32
• DSSTox Substance ID: DTXSID7061693
• Nikkaji Number: J208.526G
• Wikidata: Q18456604
• Metabolomics Workbench ID: 45779
• Mol file: 1438-91-1.mol

Synonyms:Furfuryl methyl sulfide;1438-91-1;2-((Methylthio)methyl)furan;2-(methylsulfanylmethyl)furan;Methyl furfuryl sulfide;2-Furfuryl methyl sulfide;2-[(Methylsulfanyl)methyl]furan;Furan, 2-[(methylthio)methyl]-;2-(Methylthiomethyl)furan;Furan, [(methylthio)methyl]-;FEMA No. 3160;Furan, 2-((methylthio)methyl)-;2-(Methylthio)methylfuran;2-Furfuryl methyl sulphide;2-[(methylthio)methyl]furan;UNII-LMB8355W32;LMB8355W32;EINECS 215-874-0;2-((Methylthio)methyl)-Furan;2-[(Methylthio)methyl]-Furan;Furfurylmethylsulfid;furfurylmethyl sulfide;Furfuryl methylsulfide;2-methylthiomethyl furan;2-Methylsulfanylmethyl-furan;FURFURYL METHYL SULPHIDE;SCHEMBL1357473;DTXSID7061693;FEMA 3160;2-[(Methylsulfanyl)methyl]furan #;MFCD00009604;AKOS015852531;FURFURYL METHYL SULFIDE [FHFI];Furfuryl methyl sulfide, >=97%, FG;CS-W013461;AS-59028;F0245;FT-0626579;D90650;EN300-1698611;A808129;Q-100163;Q18456604;6-fluoro-2,3-dihydro-2H,5H-spiro[imidazolidine-4,4-thiochromene]-2,5-dione

Chemical Property of Furfuryl methyl sulfide

Chemical Property:

• Appearance/Colour: clear yellow to green or light brown liquid
• Vapor Pressure: 1.58mmHg at 25°C
• Refractive Index: n20/D 1.521(lit.)
• Boiling Point: 174.9 °C at 760 mmHg
• Flash Point: 63.3 °C
• PSA: 38.44000
• Density: 1.077 g/cm³
• LogP: 2.14260
• Storage Temp.: Keep in dark place,Sealed in dry,Room Temperature
• XLogP3: 1.6
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 2
• Exact Mass: 128.02958605
• Heavy Atom Count: 8
• Complexity: 65.5

Purity/Quality:

99% ^*data from raw suppliers

MethylFurfurylSulfide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36/37/39-37/39-37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CSCC1=CC=CO1

Technology Process of Furfuryl methyl sulfide

There total 9 articles about Furfuryl methyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

(+/-)-2-furfuryl methyl sulfoxide (18185-54-1) → furfuryl methyl sulfide (1438-91-1)

Guidance literature:

With sodium tetrahydroborate; titanium tetrachloride; In 1,2-dimethoxyethane; for 0.5h; Ambient temperature;

DOI:10.1055/s-1980-29174

Reference yield: 6.0%

O-furfuryl-S-methyl dithiocarbonate (170024-06-3) → furfuryl methyl sulfide (1438-91-1) + S-furfuryl S-methyl dithiocarbonate

Guidance literature:

In benzene; for 2h; Heating;

Reference yield:

N-(1-deoxy-D-erythro-2-pentulos-1-yl)glycine → furfural (98-01-1) + furfuryl methyl sulfide (1438-91-1) + N-methylpyrrole aldehyde (1192-58-1) + perillene (539-52-6) + Dimethyldisulphide (624-92-0) + 3,6-dimethyl-2,4,5,7-tetrathiaoctane (69078-77-9)

Guidance literature:

With L-methionine; at 100 ℃; for 2h;

DOI:10.1016/j.foodchem.2021.131137

upstream raw materials:

sodium methylate

2-thiolomethyl-furan

dimethyl sulfate

(2-furyl)methyl alcohol

Refernces

• 1、 Zhan, Huan,Cui, Heping,Yu, Junhe,Hayat, Khizar,Wu, Xian,Zhang, Xiaoming,Ho, Chi-Tang. "Characteristic flavor formation of thermally processed N-(1-deoxy-α-D-ribulos-1-yl)-glycine: Decisive role of additional amino acids and promotional effect of glyoxal". . . Retrieved 2021/09/28.
• 2、 Villemin, Didier,Hachemi, Messaoud. "Potassium fluoride on alumina: A convenient synthesis of O-alkyl methyldithiocarbonates. Pyrolysis of O-benzyl-S-methyldithiocarbonates". . p. 2449 - 2459. Retrieved 2007/10/03.