CID 53384317

Base Information

Chemical Name:CID 53384317
CAS No.:12354-85-7
Molecular Formula:C₂₀H₃₀Cl₄Ir₂
Molecular Weight:796.71
Hs Code.:28439000
Mol file:12354-85-7.mol

Synonyms:AKOS027470131

Suppliers and Price of CID 53384317

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

TRC
Dichloro(pentamethylcyclopentadienyl)rhodium(III)Dimer
500mg
$ 325.00

TRC
Dichloro(pentamethylcyclopentadienyl)rhodium(III)Dimer
50mg
$ 45.00

TCI Chemical
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer >96.0%(T)
200mg
$ 138.00

TCI Chemical
(Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer >96.0%(T)
1g
$ 410.00

Strem Chemicals
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
2g
$ 894.00

Strem Chemicals
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
500mg
$ 298.00

Strem Chemicals
Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99%
100mg
$ 76.00

Sigma-Aldrich
Pentamethylcyclopentadienylrhodium(III) chloride dimer 97%
250mg
$ 184.00

Sigma-Aldrich
Pentamethylcyclopentadienylrhodium(III) chloride dimer
500mg
$ 275.00

Sigma-Aldrich
Pentamethylcyclopentadienylrhodium(III) chloride dimer 97%
1g
$ 255.00

Total 75 raw suppliers

Chemical Property of CID 53384317

Chemical Property:

Appearance/Colour:burgundy solid
Melting Point:>300 °C
PSA：0.00000
LogP:8.70200
Storage Temp.:Keep in dark place,Sealed in dry,Room Temperature
Solubility.:Chloroform (Sparingly), Methanol (Slightly)
Water Solubility.:Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:6
Rotatable Bond Count:0
Exact Mass:617.91820
Heavy Atom Count:26
Complexity:108

Purity/Quality:

99%,Rh39% ^*data from raw suppliers

Dichloro(pentamethylcyclopentadienyl)rhodium(III)Dimer ^*data from reagent suppliers

Safty Information:

Pictogram(s): Xn
Hazard Codes:Xn
Statements: 20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements: 26-36-S36-S26-24/25

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[C-]1C(=C(C(=C1C)C)C)C.C[C-]1C(=C(C(=C1C)C)C)C.[Cl-].[Cl-].[Cl-].[Cl-].[Rh+3].[Rh+3]
Uses Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Technology Process of CID 53384317

There total 25 articles about CID 53384317 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: iridium(III) chloride hydrate

: 4045-44-7
1,2,3,4,5-pentamethylcyclopentadiene

: 12354-84-6,12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

Guidance literature:: In methanol; (Ar); using Schlenk techniques; treatment of IrCl3*99H2O with C5HMe5 in MeOH according to: C.White, A. Yates, P. M. Maitlis, D. M. Heinekey, Inorg. Synth. 29 (1992) 228;
DOI:10.1016/j.jorganchem.2009.05.022

Reference yield: 96.0%

: chloro(1,5-cyclooctadiene)iridium(I) dimer

: 4045-44-7
1,2,3,4,5-pentamethylcyclopentadiene

: 12354-84-6,12354-85-7
bis[dichloro(pentamethylcyclopentadienyl)iridium(III)]

Guidance literature:: With hydrogenchloride; In further solvent(s); addn. of concd. HCl to soln. of Ir-complex in pentamethylcyclopentadiene, refluxing with stirring under Ar; leaving stirring for 2 h, crystn., filtn., washing with methanol yields first crop of crystals, further treatment of filtrate yields another batch of crystals, recrystn. from CHCl3/diethyl ether, elem. anal.;