1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

Base Information

• Chemical Name: 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex
• CAS No.: 95464-05-4
• Molecular Formula: C35H30Cl4FeP2Pd
• Molecular Weight: 816.65
• Hs Code.: 28439000
• Mol file: 95464-05-4.mol

Synonyms:[1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium(II)complex with dichloromethane;1,1'-Bis(diphenylphosphino)ferrocene-palladiumdichloride dichloromethane complex;1,1'-Bis(diphenylphosphino)ferrocene-palladium(II) dichloride dichloromethane complex;1,1-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex;

Chemical Property of 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

Chemical Property:

• Melting Point: 275-280ºC(lit.)
• PSA: 27.18000
• Density: 1 g/cm3
• LogP: 10.92180
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Chloroform (Slightly), Methanol (Slightly)
• Water Solubility.: Insoluble in water.

Purity/Quality:

99% ^*data from raw suppliers

(1,1''-Bis(diphenylphosphino)ferrocene)dichloropalladium-dichloromethane ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38-40-67-48/20/22
• Safety Statements: 23-24/25-26-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Uses: suzuki reaction 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex is used in the preparation of imidazoles, benzimidazoles, and tetrahydropyrimidines,it is also used as a catalyst for Suzuki and Stile couplings. Used as a catalyst for Suzuki and Stile couplings.

Technology Process of 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex

There total 25 articles about 1,1'-Bis(diphenylphosphino)ferrocene-palladium(II)dichloride dichloromethane complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.7%

hydrogenchloride (7647-01-0,15364-23-5) + 1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + palladium (7440-05-3) → (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4)

Guidance literature:

In tetrahydrofuran; ethanol; water; at 55 - 60 ℃; for 3h; Solvent; Temperature; Inert atmosphere;

Reference yield: 99.0%

1,1'-bis-(diphenylphosphino)ferrocene (12150-46-8) + bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) → (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4)

Guidance literature:

In benzene; (Ar); addn. of soln. of Pd(PhCN)2Cl2 in benzene to soln. of Fe(C5H4PPh2)2 in benzene; pptn. for a few minutes; stirring overnight; crystn., filtration, washing with benzene, drying under vac.;

DOI:10.1021/om050869w

Reference yield: 98.0%

Methyl methanesulfonate (66-27-3) + Pd(η2-CH2=CHCHO)(dppf) (590420-33-0) → (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride (72287-26-4,95464-05-4) + [(η3-CH2CHCH(OCH3))Pd(dppf)][CH3SO3] (646068-10-2,646068-71-5)

Guidance literature:

In further solvent(s); under N2 atm. to soln. Pd(CH2=CHCHO)(dppf) in C2D4Cl2 MeOMs was added atroom temp. and heated to 60°C; identified by NMR;

DOI:10.1021/om034122m

upstream raw materials:

1,1'-bis-(diphenylphosphino)ferrocene

diamminedichloropalladium(II)

{1,1'-bis(diphenylphosphino)ferrocene} palladium dibromide

dichloromethane

Downstream raw materials:

2-[1-(3-Nitrophenyl)ethylamino]-4-[benzimidazol-1-yl]-6-(2-methylphenyl)pyrimidine

4'-cyano-N-(4-{[2-(2-pyridinyl)ethyl]amino}phenyl)-1,1'-biphenyl-2-carboxamide

[Pd(O₂CPh)2(1,1'-bis(diphenylphosphino)ferrocene)]

[Pd(O₂CCF₂CF₃-O)2(1,1'-bis(diphenylphosphino)ferrocene)]

Refernces

• 1、 -. "Preparation method of [1, 1'-bis (diphenylphosphino) ferrocene] palladium dichloride". Paragraph 0030-0048. . Retrieved 2021/02/06.
• 2、 -. "Preparation method of palladium complex". Paragraph 0025-0032. . Retrieved 2020/07/02.