Complexes of the Platinum Metals. Part 33. Synthesis of Some Ruthenium and Osmium Sulphonate Derivatives: X-Ray Crystal Structure of Aqua(carbonyl)bis(toluene-p-sulphonato)bis(triphenylphosphine)ruthenium(II)

DOI: 10.1039/DT9880000415

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Journal of the Chemical Society, Dalton Transactions p. 415 - 420 (1988)

Update date:2022-09-26

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Authors:

Harding, Alexander P.

Robinson, Stephen D.

Henrick, Kim

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Article abstract of DOI:10.1039/DT9880000415

Sulphonic acids RSO3H (R=CH3, CF3, or C6H4CH3-p) react with the precursors (M=Ru or Os) and or in refluxing benzene or toluene to afford the complexes and respectively.The precursors and react with sulphonic acids in refluxing benzene to give the η⁶-benzene complexes 6-C6H6)(PPh3)2>.However a similar reaction in refluxing ethanol yielded .The complexes have been shown by variable-temperature 1H and 31P-<1H> n.m.r. spectroscopy to be fluxional in solution.The solid-state structure of one example, has been determined by X-ray diffraction methods.The crystals are monoclinic, space group P2₁/n, with a=24.382(5), b=18.075(4), c=10.729(2) Angstroem, β=99.03(2) grad, and Z=4.The octahedral ruthenium(II) complex contains monodentate sulphonate ligands (trans to PPh3 and CO) and an aqua ligand (trans to PPh3) with strong hydrogen-bonding interactions between the H atoms of the H2O and the non-co-ordinated oxygen atoms of the sulphonate ligands.The molecular structure is very similar to that previously reported for the alcohol dehydrogenation catalyst .

Full text of DOI:10.1039/DT9880000415

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