Complexes of the Platinum Metals. Part 33. Synthesis of Some Ruthenium and Osmium Sulphonate Derivatives: X-Ray Crystal Structure of Aqua(carbonyl)bis(toluene-p-sulphonato)bis(triphenylphosphine)ruthenium(II)

DOI: 10.1039/DT9880000415

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 415 - 420 (1988)

Update date:2022-09-26

Topics:

Authors:

Harding, Alexander P.

Robinson, Stephen D.

Henrick, Kim

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9880000415

Sulphonic acids RSO3H (R=CH3, CF3, or C6H4CH3-p) react with the precursors (M=Ru or Os) and or in refluxing benzene or toluene to afford the complexes and respectively.The precursors and react with sulphonic acids in refluxing benzene to give the η⁶-benzene complexes 6-C6H6)(PPh3)2>.However a similar reaction in refluxing ethanol yielded .The complexes have been shown by variable-temperature 1H and 31P-<1H> n.m.r. spectroscopy to be fluxional in solution.The solid-state structure of one example, has been determined by X-ray diffraction methods.The crystals are monoclinic, space group P2₁/n, with a=24.382(5), b=18.075(4), c=10.729(2) Angstroem, β=99.03(2) grad, and Z=4.The octahedral ruthenium(II) complex contains monodentate sulphonate ligands (trans to PPh3 and CO) and an aqua ligand (trans to PPh3) with strong hydrogen-bonding interactions between the H atoms of the H2O and the non-co-ordinated oxygen atoms of the sulphonate ligands.The molecular structure is very similar to that previously reported for the alcohol dehydrogenation catalyst .

Full text of DOI:10.1039/DT9880000415

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:aqua(carbonyl)bis(methanesulphonato)bis(triphenylphosphine)osmium(II)

Cas No:105811-86-7

R&D Labs maybe for 105811-86-7

Wuhan Chemchemical Co., Ltd.(expird)

Contact:15973022782

Address:7-5-6218,Incubation Centre,Guandong Industry Park, East Lake High-Tech Development Zone,Wuhan City.
WUHU HUAHAI BIOLOGY ENGINEERING CO LTD

Contact:+86-553-3836920

Address:7/F NO.82 LAODONG ROAD WUHU CHINA
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China
Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
ShiJiaZhuang Dowell Chemical Co.,Ltd.

website:http://www.dowechem.com

Contact:+86-13463963265

Address:Xiyangling village, high tech Zone, Shijiazhuang，Hebei, China

Relevant to this article

SYNTHESIS OF COMPLEX PYRIDINE BASES IN THE REACTION OF α,ω-NITRILEACETYLENES WITH ACETYLENE, CATALYZED BY COBALT COMPLEXES

Doi:10.1007/BF00954829
(1986)
Total synthesis of the latrunculins

Doi:10.1021/ja00034a036
(1992)
Synthesis of pyrazolo[1,5-c]pyrimidines from difluoroboron chelates of aroylacetones

Doi:10.1007/s11172-007-0154-5
(2007)
ENANTIODIFFERENTIATING FUNCTIONALIZATION OF 2-SUBSTITUTED 1,3-PROPANEDIOLS VIA CHIRAL SPIROKETAL: TWO METHODS FOR THE PREPARATION OF (S)-2,3-DIMETHYLBUTYL PHENYL SULFIDES

Doi:10.1016/S0040-4039(00)95573-4
(1987)
ARYLATION AND VINYLATION OF 2-CARBOETHOXYETHYLZINC IODIDE AND 3-CARBOETHOXYPROPYLZINC IODIDE CATALYZED BY PALLADIUM

Doi:10.1016/S0040-4039(00)84147-7
(1986)
THE REACTION OF TRIBUTYLSTANNYLLITHIUM WITH 2-ETHOXY-3-ALKENENITRILES. A NEW METHOD FOR THE PREPARATION OF γ-ETHOXYALLYLSTANNANES AND DIENOL ETHERS

Doi:10.1246/cl.1986.345
(1986)

Article Doi