1'-bromo-1-aminoferrocene

Base Information

Chemical Name:1'-bromo-1-aminoferrocene
CAS No.:206274-95-5
Molecular Formula:C₁₀H₁₀BrFeN
Molecular Weight:279.947
Hs Code.:

Synonyms:1'-bromo-1-aminoferrocene

Suppliers and Price of 1'-bromo-1-aminoferrocene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 1'-bromo-1-aminoferrocene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 1'-bromo-1-aminoferrocene

There total 1 articles about 1'-bromo-1-aminoferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: benzyl N-(1'-bromoferrocen-1-yl)carbamate

: 1273-82-1
aminoferrocene

: 206274-95-5
1'-bromo-1-aminoferrocene

Guidance literature:: With palladium on activated charcoal; hydrogen; In isopropyl alcohol; for 2.5h; Schlenk technique;
DOI:10.1021/acs.organomet.5b00340

Reference yield: 62.0%

: 67-56-1
methanol

: 109-72-8,29786-93-4
n-butyllithium

: 206274-95-5
1'-bromo-1-aminoferrocene

: 124-38-9,18923-20-1
carbon dioxide

: 1273-82-1
aminoferrocene

: 206275-03-8
methyl (1'-amino)ferrocenecarboxylic acid

: 206275-01-6
(C₅H₄COOCH₃)Fe(C₅H₄NH(CH₂)3CH₃)

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; diethyl ether; N2-atmosphere; addn. of 2.5 equiv. BuLi to Fe-complex soln. (in THF/Et2O-1:1) at -70°C, warming to -50°C, treatment with excess CO2, warming to room temp., quenching with H2O, drying (vac.), dissoln. inMeOH, stirring with HCl overnight; dropwise addn. of diltd. NaOH to pH=8, extn. into Et2O, drying (MgSO4), solvent removal (vac.), chromy. (Al2O3);
DOI:10.1016/S0022-328X(97)00528-7