methyl (1'-amino)ferrocenecarboxylic acid

Base Information

Chemical Name:methyl (1'-amino)ferrocenecarboxylic acid
CAS No.:206275-03-8
Molecular Formula:C₁₂H₁₃FeNO₂
Molecular Weight:259.088
Hs Code.:

Synonyms:methyl (1'-amino)ferrocenecarboxylic acid

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Chemical Property of methyl (1'-amino)ferrocenecarboxylic acid

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Technology Process of methyl (1'-amino)ferrocenecarboxylic acid

There total 1 articles about methyl (1'-amino)ferrocenecarboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

: 67-56-1
methanol

: 109-72-8,29786-93-4
n-butyllithium

: 206274-95-5
1'-bromo-1-aminoferrocene

: 124-38-9,18923-20-1
carbon dioxide

: 1273-82-1
aminoferrocene

: 206275-03-8
methyl (1'-amino)ferrocenecarboxylic acid

: 206275-01-6
(C₅H₄COOCH₃)Fe(C₅H₄NH(CH₂)3CH₃)

Guidance literature:: With hydrogenchloride; In tetrahydrofuran; diethyl ether; N2-atmosphere; addn. of 2.5 equiv. BuLi to Fe-complex soln. (in THF/Et2O-1:1) at -70°C, warming to -50°C, treatment with excess CO2, warming to room temp., quenching with H2O, drying (vac.), dissoln. inMeOH, stirring with HCl overnight; dropwise addn. of diltd. NaOH to pH=8, extn. into Et2O, drying (MgSO4), solvent removal (vac.), chromy. (Al2O3);
DOI:10.1016/S0022-328X(97)00528-7

Reference yield: 75.0%

: 206275-03-8
methyl (1'-amino)ferrocenecarboxylic acid

: 19715-19-6
3,5-ditertbutyl salicylic acid

: C₂₇H₃₃FeNO₄

Guidance literature:: With N-ethyl-N,N-diisopropylamine; N-[(dimethylamino)-3-oxo-1H-1,2,3-triazolo[4,5-b]pyridin-1-yl-methylene]-N-methylmethanaminium hexafluorophosphate; In N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;
DOI:10.1002/ejoc.201600774