IODOTRIMETHYLPLATINUM (IV)

Base Information

• Chemical Name: IODOTRIMETHYLPLATINUM (IV)
• CAS No.: 14364-93-3
• Molecular Formula: C3H9IPt
• Molecular Weight: 367.089
• Mol file: 14364-93-3.mol

Synonyms:Trimethylplatinumiodide (6CI);Iodotrimethylplatinum;Iodotrimethylplatinum(IV);

Chemical Property of IODOTRIMETHYLPLATINUM (IV)

Chemical Property:

• Melting Point: 250 °C (dec.)
• PSA: 0.00000
• LogP: -1.24710
• Storage Temp.: under inert gas (nitrogen or Argon) at 2-8°C
• Sensitive.: Air & Light Sensitive
• Water Solubility.: It is insoluble in water.It is sparingly soluble ether, alcohol, acetone or light petroleum.

Purity/Quality:

98%,Pt>53.1 ^*data from raw suppliers

Iodotrimethylplatinum(IV), 99% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: They are used as catalysts in organic reactions. It is used in chemical, organic Intermediates research. They are used as platinum group compounds for the preparation of materials suitable for industrial applications, mainly in electronics as coatings.

Technology Process of IODOTRIMETHYLPLATINUM (IV)

There total 11 articles about IODOTRIMETHYLPLATINUM (IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

potassium hexachloropalatinate(IV) + methyllithium (917-54-4) + potassium iodide (7681-11-0) → trimethylplatinum(IV) iodide (14364-93-3)

Guidance literature:

potassium hexachloropalatinate(IV); methyllithium; In tetrahydrofuran; at 0 - 20 ℃; for 4h;

With ethylene dibromide; In tetrahydrofuran; at 0 ℃; for 1h;

potassium iodide; With hydrogenchloride; In water;

DOI:10.1039/c2ce25904d

Reference yield: 75.0%

sodium hexachloroplatinate + methyl iodide (74-88-4) → trimethylplatinum(IV) iodide (14364-93-3)

Guidance literature:

With Mg; In diethyl ether; benzene; (inert atm.), Mg and Me3I in Et2O treated with dry benzene, treated withNa2PtCl6 at -20°C quickly under vigorous stirring, stirred for 2 h at 0°C; quenched to acidified H2O, aq. layer extd.(hexane), evapd.;

DOI:10.1134/S1070328411080136

Reference yield:

platinum(IV) chloride (13454-96-1) → trimethylplatinum(IV) iodide (14364-93-3) + Tetramethyl-platin(IV) (22295-11-0)

Guidance literature:

With methyl magnesium iodide; In benzene;

DOI:10.1021/ja01279a508

upstream raw materials:

methyl magnesium iodide

potassium trichloro(ethylene)platinate(II)

Zeise's salt

platinum(IV) chloride

Downstream raw materials:

[PtMe₃(SbMePh₂)2I]

[(PtMe3)2(μ-Ph2SbCH2SbPh2)(μ-I)2]

(η5-methylcyclopentadienyl)trimethylplatinum(IV)

Refernces

• 1、 Clegg,Hall. "". . p. 71,73, 74. Retrieved 1967.
• 2、 Zharkova,Baidina,Turgambaeva,Romanenko,Igumenov. "Volatile fluorinated trimethylplatinum(IV) β-diketonates: Synthesis, properties, and structure". . p. 40 - 45. Retrieved 2012.
• 3、 Baldwin, James C.,Kaska, William C.. "Improved isolation procedure for the preparation of iodo(trimethyl)platinum(IV)". . p. 2020 - 2020. Retrieved 2007/10/18.