TIN (II) ETHOXIDE

Base Information

• Chemical Name: TIN (II) ETHOXIDE
• CAS No.: 14791-99-2
• Molecular Formula: C₄H₁₀O₂Sn
• Molecular Weight: 208.832
• Hs Code.: 2917110099
• Mol file: 14791-99-2.mol

Synonyms:Ethylalcohol, tin(2+) salt (8CI);Tin diethoxide;Tin(2+) ethoxide;Diethoxytin;

Chemical Property of TIN (II) ETHOXIDE

Chemical Property:

• Melting Point: 200 °C (dec.)
• PSA: 18.46000
• LogP: 0.59360
• Sensitive.: Air & Moisture Sensitive
• Water Solubility.: Reacts with water

Purity/Quality:

98%Min ^*data from raw suppliers

Tin(II) ethoxide, min. 99% ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Tin(II) ethoxide is used in catalyst synthesis.

Technology Process of TIN (II) ETHOXIDE

There total 10 articles about TIN (II) ETHOXIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

methanol (67-56-1) + sodium (7440-23-5) + bis(1-ethoxy-1,3-butanedionato)tin(II) → tin(II) bis(methoxide) (14794-99-1,27961-67-7) + tin(II) ethoxide (3173-69-1,14791-99-2,24126-00-9,96473-13-1)

Guidance literature:

In methanol; benzene; byproducts: Na(C2H5OC(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(etac)2 in C6H6 to soln. of Na in MeOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;

DOI:10.1080/00945719708000227

Reference yield: 51.0%

ethanol (64-17-5) + sodium (7440-23-5) + bis(1-ethoxy-1,3-butanedionato)tin(II) → tin(II) ethoxide (3173-69-1,14791-99-2,24126-00-9,96473-13-1)

Guidance literature:

In ethanol; benzene; byproducts: Na(C2H5OC(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(etac)2 in C6H6 to soln. of Na in EtOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;

DOI:10.1080/00945719708000227

Reference yield: 45.0%

ethanol (64-17-5) + sodium (7440-23-5) + bis(2,4-pentanedionato)tin(II) → tin(II) ethoxide (3173-69-1,14791-99-2,24126-00-9,96473-13-1)

Guidance literature:

In ethanol; benzene; byproducts: Na(CH3C(O)CHC(O)CH3); N2 atmosphere; addn. of soln. of Sn(acac)2 in C6H6 to soln. of Na in EtOH (Sn : Na = 1 : 2, stirring, room temp.), stirring (0.5 h; pptn.); filtration, washing (MeOH, benzene), drying (vac.); elem. anal.;

DOI:10.1080/00945719708000227

upstream raw materials:

ethanol

methanol

sodium

tin

Downstream raw materials:

acetaldehyde

crotonaldehyde

2C₉H₁₀NOS^(1-)*Sn⁽²⁺⁾

orthocarbonic acid tetraethyl ester

Refernces

• 1、 Wakeshima, Ikuko,Suzuki, Toshitaka,Takemoto, Akihiko,Kijima, Ichiro. "A new method for synthesizing dialkoxytin(II) and mono and diaryloxytin(II) compounds". . p. 787 - 796. Retrieved 2008/10/09.