ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

Base Information

Chemical Name:ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate
CAS No.:1564265-54-8
Molecular Formula:C₃₀H₂₈O₃
Molecular Weight:436.551
Hs Code.:

Synonyms:ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

Chemical Property:

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Technology Process of ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

There total 5 articles about ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

: 201230-82-2
carbon monoxide

: 61440-87-7
C₁₈H₁₈

: 2216-94-6
phenylpropynoic acid ethyl ester

: 1564265-54-8
ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

Guidance literature:: With copper dichloride; palladium dichloride; In dichloromethane; at 40 ℃; under 760.051 Torr;
DOI:10.1039/c3cc48308h

Reference yield:

: 623-47-2
propynoic acid ethyl ester

: 1564265-54-8
ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide; silver(l) oxide; caesium carbonate / 1,2-dichloro-ethane / 36 h / 80 °C

2: palladium dichloride; copper dichloride / dichloromethane / 40 °C / 760.05 Torr

With copper(l) iodide; caesium carbonate; copper dichloride; palladium dichloride; silver(l) oxide; In dichloromethane; 1,2-dichloro-ethane;
DOI:10.1039/c3cc48308h

Reference yield:

: 4214-28-2
1-iodo-2,4-dimethylbenzene

: 1564265-54-8
ethyl 4,5-bis(2,4-dimethylphenyl)-3-oxo-2-phenylcyclopenta-1,4-dienecarboxylate

Guidance literature:: Multi-step reaction with 2 steps

1: copper(l) iodide; bis-triphenylphosphine-palladium(II) chloride; triethylamine / tetrahydrofuran / 20 °C / Inert atmosphere

2: palladium dichloride; copper dichloride / dichloromethane / 40 °C / 760.05 Torr

With bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine; copper dichloride; palladium dichloride; In tetrahydrofuran; dichloromethane;
DOI:10.1039/c3cc48308h