poly(butadiene)

Base Information

• Chemical Name: poly(butadiene)
• CAS No.: 63394-00-3
• Molecular Formula: Cl₂Mg
• Molecular Weight: 95.211
• Mol file: 63394-00-3.mol

Synonyms:

Chemical Property of poly(butadiene)

Chemical Property:

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of poly(butadiene)

There total 202 articles about poly(butadiene) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

magnesium (7439-95-4) + zinc(II) chloride (7646-85-7,24359-56-6) → magnesium chloride (7786-30-3)

Guidance literature:

In melt; melting the starting materials in an evacuated silica ampoule at 900°C for 48 h, cracking the ampoule under Ar;

DOI:10.1016/S0020-1693(00)86661-X

Reference yield: 93.0%

magnesium silicide (22831-39-6) + ammonium chloride → silicon nitride + ammonia (7664-41-7) + hydrogen (1333-74-0) + magnesium chloride (7786-30-3)

Guidance literature:

In neat (no solvent); High Pressure; mixed, sealed in autoclave under Ar, heated at 450, 500, 550, and 600 °C for 10 h; washed with water, dried in vac. at 70 °C for 12 h; powder XRD;

DOI:10.1111/j.1551-2916.2004.01810.x

Reference yield: 50.0%

magnesium (7439-95-4) + calcium chloride (14336-71-1) → hydrogen (1333-74-0) + magnesium chloride (7786-30-3) + calcium hydroxide

Guidance literature:

With water; In neat (no solvent); reduction of dry CaCl2 in H2-atmosphere on calcination with Mg; treatment of the reaction-products with H2O under formation of H2;;

upstream raw materials:

ethylmagnesium chloride

methyltrichlorogermane

isopropylmagnesium chloride

triethylaluminum

Refernces

• 1、 Kishimoto, Akihiro,Uda, Tetsuya. "In-situ observation on the magnesiothermic reduction of TiCl4 around 800 °C by microfocus X-ray fluoroscopy". . . Retrieved 2021.
• 2、 Rodionov,Maizlish,Shaposhnikov. "Synthesis and properties of tetra-(4-tert-butyl-5-nitro)phthalocyanines". . p. 96 - 101. Retrieved 2016.
• 3、 Chai, Shu-Jing,Luo, Bi-Jun,Wu, Hai-Hong,Wu, Dan,Lu, Shao-Yan,Zhang, Qi. "Controlled synthesis of Mg(OH)2 nanorods using basic magnesium chloride as precursor". . p. 90 - 101. Retrieved 2021.
• 4、 Kanari,Gaballah,Allain. "Kinetics of oxychlorination of chromite Part I. Effect of temperature". . p. 143 - 154. Retrieved 2001.
• 5、 Kanari,Gaballah,Allain. "Determination of temperature effect of oxychlorination of Cr2O3 and MgO using non-isothermal conditions". . p. 131 - 137. Retrieved 2000.
• 6、 Congwen, Duan,Lianxi, Hu,Yu, Sun. "Effect of Zn and Zr addition on the synthesis of an AlH3/MgCl2 nanocomposite and its de-hydriding properties". . p. 17104 - 17108. Retrieved 2015.
• 7、 Maslennikov,Sergeeva,Spirina,Kazakina. "Oxidation of magnesium with benzoyl chloride in a mixture of tetrahydrofuran and benzene". . p. 678 - 680. Retrieved 2002.
• 8、 Finch, William C.,Gillespie, Ralph D.,Hedden, David,Marks, Tobin J.. "Organometallic molecule-inorganic surface coordination and catalytic chemistry. In Situ CPMAS NMR delineation of organoactinide adsorbate structure, dynamics, and reactivity". . p. 6221 - 6232. Retrieved 1990.
• 9、 Rognerud, Erik G.,Rom, Christopher L.,Todd, Paul K.,Singstock, Nicholas Ryan,Bartel, Christopher J.,Holder, Aaron M.,Neilson, James R.. "Kinetically Controlled Low-Temperature Solid-State Metathesis of Manganese Nitride Mn3N2". . p. 7248 - 7254. Retrieved 2019.
• 10、 Bevers,Oonk,Haije,Van Ekeren. "Investigation of thermodynamic properties of magnesium chloride amines by HPDSC and TG: For application in a high-lift high-temperature chemical heat pump". . p. 923 - 929. Retrieved 2007.