ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

Base Information

Chemical Name:ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate
CAS No.:88765-79-1
Molecular Formula:C₁₆H₃₀BNO₂Si₂
Molecular Weight:335.402
Hs Code.:

Synonyms:ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

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Chemical Property of ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

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Technology Process of ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

There total 2 articles about ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 88765-78-0
ethylene glycol 1-chloro-2-phenylethane-1-boronate

: 4039-32-1
lithium hexamethyldisilazane

: 88765-79-1
ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

Guidance literature:: In tetrahydrofuran; byproducts: LiCl; one equiv. of boronate added to LiN(SiMe3)2 in THF at -78°C, mixt. kept overnight at 20°C; product distd. from LiCl;
DOI:10.1021/ja00407a051

Reference yield: 85.0%

: 88765-78-0
ethylene glycol 1-chloro-2-phenylethane-1-boronate

: 999-97-3
1,1,1,3,3,3-hexamethyl-disilazane

: 88765-79-1
ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

Guidance literature:: With n-butyllithium; In tetrahydrofuran; a soln. of (Me3Si)2NLi, prepd. from (Me3Si)2NH and BuLi in THF, was treated with the boronate at -78°C, mixt. was kept overnight; mixt. was distilled directly followed by redistn.; elem. anal.;
DOI:10.1021/om00082a019

Reference yield: 86.0%

: 88765-79-1
ethylene glycol 1-(bis(trimethylsilyl)amino)-2-phenylethane-1-boronate

: 88765-80-4
ethylene glycol 1-acetamido-2-phenylethane-1-boronate

Guidance literature:: With acetic anhydride; acetic acid; In tetrahydrofuran; a soln. of silylamino deriv. in THF was stirred at -78°C during the dropwise addn. of Ac2O followed by AcOH, mixt. was left overnight at25°C; distilled, distillate solidified and was sublimed at 70°C (0.04 Torr); elem. anal.;
DOI:10.1021/om00082a019