3-CHLOROALLYLTRIMETHYLSILANE

Base Information

• Chemical Name: 3-CHLOROALLYLTRIMETHYLSILANE
• CAS No.: 18187-39-8
• Molecular Formula: C6H13 Cl Si
• Molecular Weight: 148.708
• Hs Code.: 2931900090
• Mol file: 18187-39-8.mol

Synonyms:Silane,(3-chloro-2-propenyl)trimethyl- (9CI); Silane, (3-chloroallyl)trimethyl-(6CI,8CI); (3-Chloroallyl)trimethylsilane; 1-Chloro-3-(trimethylsilyl)propene

Chemical Property of 3-CHLOROALLYLTRIMETHYLSILANE

Chemical Property:

• Refractive Index: n20/D 1.444(lit.)
• Boiling Point: 137 °C736 mm Hg(lit.)
• Flash Point: 73 °F
• PSA: 0.00000
• Density: 0.898 g/mL at 25 °C(lit.)
• LogP: 3.07710
• Storage Temp.: 2-8°C

Purity/Quality:

99%min ^*data from raw suppliers

3-CHLOROALLYL-TRIMETHYL-SILANE 95.00% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,C
• Statements: 11-34-37
• Safety Statements: 26-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 3-CHLOROALLYLTRIMETHYLSILANE

There total 4 articles about 3-CHLOROALLYLTRIMETHYLSILANE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

3-chloroallyltrichlorosilane (18083-15-3) + methylmagnesium bromide (75-16-1) → 1-chloro-3-trimethylsilylpropene (18187-39-8)

Guidance literature:

In diethyl ether;

DOI:10.1039/c39800001118

Reference yield: 40.0%

chloro-trimethyl-silane (75-77-4) + E/Z-1,3-Dichloropropene (542-75-6) → 1-chloro-3-trimethylsilylpropene (18187-39-8) + (1-chloroprop-2-enyl)trimethyl silane (67965-28-0)

Guidance literature:

With magnesium; ethylene dibromide; In tetrahydrofuran; diethyl ether; for 4h; Yields of byproduct given. Title compound not separated from byproducts; Ambient temperature;

DOI:10.1246/bcsj.57.3017

Reference yield:

trans-1-Trimethylsilyl-2-chlor-cyclopropan → 1-chloro-3-trimethylsilylpropene (18187-39-8)

Guidance literature:

(thermolysis);

upstream raw materials:

3-chloroallyltrichlorosilane

methylmagnesium chloride

chloro-trimethyl-silane

E/Z-1,3-Dichloropropene

Downstream raw materials:

2-Chloro-1-phenyl-but-3-en-1-one

(Diphenylphosphinyloxy)trimethylsilan

3-Chloro-1-phenyl-pent-4-en-2-one

2-Chloro-1-cyclohexyl-but-3-en-1-one

Refernces

• 1、 Shimizu, Nobujiro,Shibata, Fumihiro,Tsuno, Yuho. "Synthesis and Reactions of 1-(Trimethylsilyl)allyl Chloride". . p. 3017 - 3018. Retrieved 2007/10/02.