(Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

Base Information

• Chemical Name: (Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2
• CAS No.: 495413-29-1
• Molecular Formula: C₁₂₂H₁₄₂N₈O₂Si₂Zn₂
• Molecular Weight: 1939.47

Synonyms:(Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

Chemical Property of (Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

Chemical Property:

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Technology Process of (Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2

There total 1 articles about (Zn(C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C(C₆H₄CH₂OSi(CH₃)2C(CH₃)3)C₄NH₂C(C₆H₃(C(CH₃)3)2)C₄NH₂C))2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) (220355-79-3) + 2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (495402-49-8) → (Zn(C4NH2C(C6H3(C(CH3)3)2)C4NH2C(C6H4CH2OSi(CH3)2C(CH3)3)C4NH2C(C6H3(C(CH3)3)2)C4NH2C))2 (495413-29-1)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; caesium carbonate; In toluene; mixt. refluxed in C6H5CH3 for 18 h;

DOI:10.1039/b206624f

Reference yield: 84.0%

(Zn(C4NH2C(C6H3(C(CH3)3)2)C4NH2C(C6H4CH2OSi(CH3)2C(CH3)3)C4NH2C(C6H3(C(CH3)3)2)C4NH2C))2 (495413-29-1) + water (7732-18-5) → μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II) (866321-88-2)

Guidance literature:

With (C₄H₉)4NF; In tetrahydrofuran; N2 atm.; several drops of 1 M soln. of (C4H9)4NF in THF were added at 0°C to a soln. of complex in THF, the mixt. was stirred for 30 min at 0°C and 1 h at 25°C; CHCl3 was added followed by H2O, the organic layer was washed with H2O, satd. aq. NaCl, dried (Na2SO4), evapd. in vac.; flash chromy. (silica gel; cyclohexane/CH2Cl2 1:1, 1% v/v (C2H5)3N), pptn. from CHCl3 by addn. of methanol/H2O 9:1;

DOI:10.1002/hlca.200590144

Reference yield: 67.0%

(Zn(C4NH2C(C6H3(C(CH3)3)2)C4NH2C(C6H4CH2OSi(CH3)2C(CH3)3)C4NH2C(C6H3(C(CH3)3)2)C4NH2C))2 (495413-29-1) + ethyl chlorocarbonylacetate (36239-09-5) → μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc (495413-32-6)

Guidance literature:

With tetrabutyl ammonium fluoride; triethylamine; In dichloromethane; mixt. of Zn-complex, (C4H9)4NF reacted in CH2Cl2 at rt for 3 h; soln. ofC2H5OOCCH2COCl, (C2H5)3N in CH2Cl2 added; mixt reacted for 1.5 h at roo m temp.;

DOI:10.1039/b206624f

upstream raw materials:

μ-[15,15'-diiodo-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

2-[3-({[(tert-butyl)(dimethyl)silyl]oxy}methyl)phenyl]-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

Downstream raw materials:

μ-[15,15'-bis(3-[[(3-ethoxy-3-oxopropanoyl)oxy]methyl]phenyl)-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),κN(24')]dizinc

μ-[15,15'-bis[3-(hydroxymethyl)phenyl]-10,10',20,20'-tetrakis[3,5-di(tert-butyl)phenyl]-5,5'-biporphyrinato(4-)-κN(21),κN(22),κN(23),κN(24),κN(21'),κN(22'),κN(23'),.kappaN(24')]dizinc(II)

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