Tris(2,2'-bipyridyl)ruthenium(II)

Base Information

• Chemical Name: Tris(2,2'-bipyridyl)ruthenium(II)
• CAS No.: 15158-62-0
• Molecular Formula: C₃₀H₂₄N₆Ru
• Molecular Weight: 569.631
• Wikidata: Q27123697
• Mol file: 15158-62-0.mol

Synonyms:Ru(bPy)3 Cl2;Ru(II)(bpy)3;tris(2,2'-bipyridyl)dichlororuthenium(II) hexahydrate;tris(2,2'-bipyridyl)dichlororuthenium(III);tris(2,2'-bipyridyl)ruthenium(II)

Chemical Property of Tris(2,2'-bipyridyl)ruthenium(II)

Chemical Property:

• Boiling Point: 272.5°Cat760mmHg
• Flash Point: 107.2°C
• PSA: 77.34000
• Density: g/cm³
• LogP: 6.43080
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 570.110585
• Heavy Atom Count: 37
• Complexity: 120

Purity/Quality:

99% ^*data from raw suppliers

TRIS-(2,2'-BIPYRIDYL)RUTHENIUM-(II)-DICHLORIDE-N-HYDRATE 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.C1=CC=NC(=C1)C2=CC=CC=N2.[Ru+2]

Technology Process of Tris(2,2'-bipyridyl)ruthenium(II)

There total 23 articles about Tris(2,2'-bipyridyl)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

tris(2,2’-bipyridyl)ruthenium(III) perchlorate + water (7732-18-5) → tris(2,2’-bipyridine)ruthenium(II) (52389-25-0,24162-12-7,15158-62-0) + carbon dioxide (124-38-9,18923-20-1) + oxygen (80937-33-3)

Guidance literature:

With sulfuric acid; ruthenium(IV) oxide; In sulfuric acid; bubbling Ar through react. vessel, outgasing solns. under vac. before shaking; mixing soln. of Ru-compd. with aq. H2SO4 soln. (pH 1.2) containing colloidal RuO2 with stirring at 20°C; gas chromy. anal.;

Reference yield:

tris-2,2'-bipyridyl ruthenium(III) ion (18955-01-6,104759-03-7,24162-13-8) + 18O-labeled water (14797-71-8) → tris(2,2’-bipyridine)ruthenium(II) (52389-25-0,24162-12-7,15158-62-0) + oxygen-18 (32767-18-3)

Guidance literature:

Rb8K2[Ru4O4(OH)2(H2O)4(γ-SiW10O36)2]*25H2O; In water-d2; byproducts: H(1+); H2(18)O reacted with Ru(NC5H4C5H4N)3(3+) in presence of small amt. of Ru-W complex; monitored by chromy.;

DOI:10.1002/anie.200705652

Reference yield:

tris-2,2'-bipyridyl ruthenium(III) ion (18955-01-6,104759-03-7,24162-13-8) + hypophosphorous acid (6303-21-5) → phosphonic Acid (13598-36-2) + tris(2,2’-bipyridine)ruthenium(II) (52389-25-0,24162-12-7,15158-62-0)

Guidance literature:

With water; In sulfuric acid; in 1 M H2SO4; not isolated, detected by UV; Kinetics;

DOI:10.1021/jp0602575

upstream raw materials:

water

tris-2,2'-bipyridyl ruthenium(III) ion

hypophosphorous acid

dimercury⁽²⁺⁾

Downstream raw materials:

tris-2,2'-bipyridyl ruthenium(III) ion

hydrogen

cis-dichlorobis(2,2′-bipyridine)ruthenium(II)

ruthenium(III)