(η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

Base Information

Chemical Name:(η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese
CAS No.:530151-29-2
Molecular Formula:C₂₁H₁₅MnO₅S
Molecular Weight:434.351
Hs Code.:

Synonyms:(η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

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Chemical Property of (η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

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Technology Process of (η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

There total 1 articles about (η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 458566-05-7
(η5-1-chloro-4-methoxy-6-phenylcyclohexadienyl)tricarbonylmanganese

: 201230-82-2
carbon monoxide

: 54663-78-4
tributyl(thien-2-yl)stannane

: 530151-29-2
(η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

Guidance literature:: With Pd₂(dba)3; AsPh₃; In tetrahydrofuran; (N2); using Schlenk techniques; addn. of Pd2(dba)3 and AsPh3 to soln. ofMn(CO)3(ClC6H4(Ph)OMe) in anhyd. THF, pulling of CO through react. mixt ., addn. of 2-tributylstannylthiophene, stirring for 3 h at reflux; addn. of cold ice water, extn. twice with Et2O, washing with water of combined org. phases, drying over MgSO4, filtration, evapn. under nitrogenflush, flash chromy. on silica gel (petroleuum ether/Et2O, 80:20), elem . anal.;
DOI:10.1021/om021017o

Reference yield: 86.0%

: 530151-29-2
(η5-1-C(O)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

: 7732-18-5
water

: 676-58-4
methylmagnesium chloride

: 1012785-86-2,1013331-87-7
(η5-1-C(OH)(Me)(2-thienyl)-4-OMe-6-phenyl-cyclohexadienyl)tricarbonylmanganese

Guidance literature:: In tetrahydrofuran; under N2; MeMgCl added at 0°C to soln. of Mn complex in THF; stirred at 0°C for 20 min; H2O added; aq. phase extd. (Et2O); org. phase washed (H2O, satd. aq. NaCl); dried (MgSO4); solvent removed under reduced pressure; dried in vac.; purified by column chromy. (silica gel, petroleum ether-Et2O); two diastereoisomers obtained; elem. anal.;
DOI:10.1021/om7010672