Chromium fluoride

Base Information

• Chemical Name: Chromium fluoride
• CAS No.: 11113-56-7
• Molecular Weight: 0
• Mol file: 11113-56-7.mol

Synonyms:Chromium(III) fluoride, anhydrous; chromium trifluoride; Chromic Fluoride; Chromiumfluorideanhydrousgreenpowder; Chromiumfluoride; chromium(3+) trifluoride; difluoro(dioxo)chromium; chromous trifluoride; Chromium fluoride

Chemical Property of Chromium fluoride

Chemical Property:

• Melting Point: 1000℃
• PSA: 0.00000
• LogP: 0.00000

Purity/Quality:

98%,99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Chromium fluoride

There total 8 articles about Chromium fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fluoropentaamminecobalt(III) perchlorate + [Co(NH3)5Cl](2+)*2ClO4(1-) = [Co(NH3)5Cl](ClO4)2 + {(H2O)5CrCH(CH3)OC2H5}(2+) → CrF(2+) (19425-73-1,11113-56-7) + CrCl(2+) (14931-91-0) + fluoride (16984-48-8) + chloride (16887-00-6) + cobalt(II) (22541-53-3,65860-59-5)

Guidance literature:

With lithium perchlorate; In water; 25°C, oxygen-free conditions, ionic strength 1.0 M; Kinetics;

Reference yield:

tris(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)chromium(III) → chromium monofluoride (13943-42-5,11113-56-7) + chromium (7440-47-3)

Guidance literature:

In gas; byproducts: CH; Irradiation (UV/VIS); laser pulses (308 or 343 nm, 0.3-30 mJ/pulse); not isolated, detd. by luminesecence spectroscopy;

DOI:10.1021/ic971340x

Reference yield:

fluoropentaamminecobalt(III) perchlorate + (H2O)5CrC(CH3)2OH(2+) + tris(ethylenediamine)cobalt(III) perchlorate → CrF(2+) (19425-73-1,11113-56-7) + fluoride (16984-48-8) + cobalt(II) (22541-53-3,65860-59-5)

Guidance literature:

With lithium perchlorate; In water; 25°C, oxygen-free conditions, ionic strength 1.0 M; Kinetics;

upstream raw materials:

chromium(III) fluoride

carbon tetrafluoride

chromium

sulfur(VI) hexafluoride

Refernces

• 1、 Koivisto,Launila,Schimmelpfennig,Simard,Wahlgren. "Spectroscopy and MRCI calculations on CrF and CrCl". . p. 8855 - 8866. Retrieved 2001.
• 2、 Talaga, David S.,Hanna, Stephen D.,Zink, Jeffrey I.. "Luminescent Photofragments of (1,1,1,5,5,5-Hexafluoro-2,4-pentanedionato) Metal Complexes in the Gas Phase". . p. 2880 - 2887. Retrieved 2008/10/08.