[Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]

Base Information

• Chemical Name: [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]
• CAS No.: 202214-22-0
• Molecular Formula: C₁₆H₂₀NRhS₂
• Molecular Weight: 393.379
• Mol file: 202214-22-0.mol

Synonyms:[Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]

Chemical Property of [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)]

There total 1 articles about [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + HN(C2H5)3(1+)*S2CN(CH3)C6H5(1-)=[HN(C2H5)3](S2CN(CH3)C6H5) (83073-99-8) → [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)] (202214-22-0)

Guidance literature:

In dichloromethane; N2-atmosphere; stirring stoich. amts. for 30 min; evapn., MeOH addn., collection (filtration), washing (cold MeOH), drying(vac.); elem. anal.;

DOI:10.1021/ic971053t

Reference yield: 73.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + silver tetrafluoroborate (14104-20-2) + [Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)] (202214-22-0) → [Rh2(μ-N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)2]BF4 (202214-27-5)

Guidance literature:

With acetone; In acetone; N2-atmosphere; treatment of dichlorocomplex with AgBF4, addn. of dithiocarbamate complex, stirring for 15 min; partial evapn., pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1021/ic971053t

Reference yield: 71.0%

[Rh(N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)] (202214-22-0) + carbon monoxide (201230-82-2) → [Rh(N-methyl,N-phenyl-dithiocarbamate)(CO)2] (202214-24-2)

Guidance literature:

In dichloromethane; absence of air and moisture; bubbling CO through soln. of Rh-complex for30 min; concn., pptn. on Et2O addn., collection (filtration), washing (cold Et2O), drying (vac.); elem. anal.;

DOI:10.1021/ic971053t

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

HN(C₂H₅)3⁽¹⁺⁾*S₂CN(CH₃)C₆H₅^(1-)=[HN(C₂H₅)3](S₂CN(CH₃)C₆H₅)

Downstream raw materials:

[Rh2(μ-N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)2]BF4

[Rh(N-methyl,N-phenyl-dithiocarbamate)(CO)2]

[Rh2(μ-N-methyl,N-phenyl-dithiocarbamate)(1,5-cyclooctadiene)(CO)2]BF4