1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

Base Information

Chemical Name:1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol
CAS No.:142563-77-7
Molecular Formula:C₄₇H₅₀O₁₁Si
Molecular Weight:818.993
Hs Code.:

Synonyms:1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

Chemical Property:

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Technology Process of 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

There total 11 articles about 1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 107-30-2
chloromethyl methyl ether

: 142534-57-4
1D-1-O-(tert-butyldiphenylsilyl)-3,4,5-O-trisbenzoyl-myo-inositol

: 142563-77-7
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

Guidance literature:: With N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide; at 50 ℃; for 2h;
DOI:10.1021/ja00042a011

Reference yield:

: 142534-54-1
1D-1-O-(tert-butyldiphenylsilyl)-myo-inositol

: 142563-77-7
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

Guidance literature:: Multi-step reaction with 2 steps

1: 92 percent / pyridine / -40 °C

2: 75 percent / diisopropylethylamine / dimethylformamide

With pyridine; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide;
DOI:10.1021/jo0206418

Reference yield:

: 87-89-8
D-myo-inositol

: 142563-77-7
1D-1-O-(tert-butyldiphenylsilyl)-2,6-O-bis(methoxymethylene)-3,4,5-O-trisbenzoyl-myo-inositol

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) TMS-triflate, 4.) p-TsOH

2: 88 percent / imidazole, pyridine / 24 h / -10 °C

3: 80 percent / mercaptoethanol, BF₃-etherate / 2.5 h / Ambient temperature

4: 89 percent / pyridine / 2 h / -10 °C

5: 75 percent / diisopropylethylamine / dimethylformamide / 2 h / 50 °C

With pyridine; 1H-imidazole; mercaptoethyl alcohol; trimethylsilyl trifluoromethanesulfonate; boron trifluoride diethyl etherate; toluene-4-sulfonic acid; N-ethyl-N,N-diisopropylamine; In N,N-dimethyl-formamide;
DOI:10.1021/ja00042a011