(+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Base Information

Chemical Name:(+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal
CAS No.:97855-71-5
Molecular Formula:C₁₅H₂₆O₂
Molecular Weight:238.37
Hs Code.:

Synonyms:(+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Suppliers and Price of (+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 1 raw suppliers

Chemical Property of (+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

There total 13 articles about (+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 110654-68-7
(1S,2S)-2-Allyl-1,3,3-trimethyl-cyclohexanecarbaldehyde

: 107-21-1
ethylene glycol

: 97855-71-5
(+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Guidance literature:: With toluene-4-sulfonic acid; In benzene; for 0.333333h; Heating;

Reference yield:

: 110715-80-5
(-)-(1S,8aS)-1,2,3,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalen-1-ol

: 97855-71-5
(+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Guidance literature:: Multi-step reaction with 11 steps

1: 95 percent / H₂ / Adam's catalyst / acetic acid

2: 90 percent / Florisil, PCC / CH₂Cl₂ / 2 h / Ambient temperature

3: 97 percent / PBB / acetic acid / 2 h / Ambient temperature

4: 97 percent / sodium hydroxide / dimethylformamide; H₂O / 0.5 h / Ambient temperature

5: lead tetra-acetate (LTA) / benzene / 0.17 h / Ambient temperature

6: NaBH₄ / methanol / 0.33 h / Ambient temperature

7: 98 percent / tributylphosphine / tetrahydrofuran / 0.33 h / Ambient temperature

8: 91 percent / hydrogen peroxide / tetrahydrofuran / 10 h / Ambient temperature

9: 1.) lithium aluminium hydride; 2.) sodium hydroxide / 1.) diethyl ether, rt, 30 min; 2.) water, 30 min.

10: 88 percent / Florisil, PCC / CH₂Cl₂ / 1 h / Ambient temperature

11: 98 percent / toluene-p-sulphonic acid / benzene / 0.33 h / Heating

With lead(IV) acetate; sodium hydroxide; sodium tetrahydroborate; florisil; lithium aluminium tetrahydride; tributylphosphine; hydrogen; dihydrogen peroxide; toluene-4-sulfonic acid; pyridinium chlorochromate; platinum(IV) oxide; In tetrahydrofuran; methanol; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; benzene;

Reference yield:

: 110654-75-6
(+)-(4aS,5S)-5-benzoyloxy-3,4,4a,5,6,7-hexahydro-1,1,4a-trimethylnaphthalen-2(1H)-one

: 97855-71-5
(+)-(1S,2S)-2-allyl-1,3,3-trimethylcyclohexanecarbaldehyde ethylene acetal

Guidance literature:: Multi-step reaction with 12 steps

1: 93 percent / potassium hydroxide, hydrazine hydrate / bis-(2-hydroxy-ethyl) ether / 6 h / Heating

2: 95 percent / H₂ / Adam's catalyst / acetic acid

3: 90 percent / Florisil, PCC / CH₂Cl₂ / 2 h / Ambient temperature

4: 97 percent / PBB / acetic acid / 2 h / Ambient temperature

5: 97 percent / sodium hydroxide / dimethylformamide; H₂O / 0.5 h / Ambient temperature

6: lead tetra-acetate (LTA) / benzene / 0.17 h / Ambient temperature

7: NaBH₄ / methanol / 0.33 h / Ambient temperature

8: 98 percent / tributylphosphine / tetrahydrofuran / 0.33 h / Ambient temperature

9: 91 percent / hydrogen peroxide / tetrahydrofuran / 10 h / Ambient temperature

10: 1.) lithium aluminium hydride; 2.) sodium hydroxide / 1.) diethyl ether, rt, 30 min; 2.) water, 30 min.

11: 88 percent / Florisil, PCC / CH₂Cl₂ / 1 h / Ambient temperature

12: 98 percent / toluene-p-sulphonic acid / benzene / 0.33 h / Heating

With lead(IV) acetate; potassium hydroxide; sodium hydroxide; sodium tetrahydroborate; florisil; lithium aluminium tetrahydride; tributylphosphine; hydrogen; dihydrogen peroxide; toluene-4-sulfonic acid; hydrazine hydrate; pyridinium chlorochromate; platinum(IV) oxide; In tetrahydrofuran; methanol; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; diethylene glycol; benzene;