Dimethylammonium formate

Base Information

• Chemical Name: Dimethylammonium formate
• CAS No.: 33978-97-1
• Molecular Formula: CH₂O₂*C₂H₇N
• Molecular Weight: 91.11
• Mol file: 33978-97-1.mol

Synonyms:dimethylamine;dimethylamine hydrochloride;dimethylamine monosulfate;dimethylamine nitrate;dimethylamine perchlorate;dimethylamine phosphate (3:1);dimethylamine sulfate;dimethylamine sulfate (1:1);dimethylamine, conjugate acid;dimethylammonium chloride;dimethylammonium formate

Chemical Property of Dimethylammonium formate

Chemical Property:

• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 91.063328530
• Heavy Atom Count: 6
• Complexity: 10.3

Purity/Quality:

99% ,98%,Electron Grade , ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[NH2+]C.C(=O)[O-]

Technology Process of Dimethylammonium formate

There total 3 articles about Dimethylammonium formate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 31.0%

DIMCARB (4137-10-4) → methanol (67-56-1) + dimethylammonium formate (33978-97-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7)

Guidance literature:

With potassium phosphate; carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)amino]ruthenium(II); hydrogen; In tetrahydrofuran; dimethyl amine; at 95 - 155 ℃; for 18h; under 37503.8 Torr; Temperature; Catalytic behavior; Inert atmosphere; Sealed tube;

DOI:10.1021/ja511329m

Reference yield: 27.0%

carbon dioxide (124-38-9,18923-20-1) + dimethyl amine (124-40-3) → methanol (67-56-1) + dimethylammonium formate (33978-97-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7)

Guidance literature:

With potassium phosphate; carbonylhydrido(tetrahydroborato)[bis(2-diphenylphosphinoethyl)amino]ruthenium(II); hydrogen; In tetrahydrofuran; at 95 - 155 ℃; for 36h; under 37503.8 Torr; Time; Solvent; Catalytic behavior; Inert atmosphere; Sealed tube;

DOI:10.1021/ja511329m

Reference yield:

carbon dioxide (124-38-9,18923-20-1) + dimethyl amine (124-40-3) → dimethylammonium formate (33978-97-1) + N,N-dimethyl-formamide (68-12-2,33513-42-7)

Guidance literature:

With hydrogen; In water; at 140 ℃; for 15h; under 30003 Torr; Flow reactor;

DOI:10.1002/cssc.201903364

upstream raw materials:

carbon dioxide

dimethyl amine

DIMCARB

Downstream raw materials:

2-(10-Dimethylamino-decyl)-5,6-dimethoxy-3-methyl-[1,4]benzoquinone; hydrochloride