Technology Process of (C6H5)3SnS(CH2)3SSn(C6H5)3
There total 1 articles about (C6H5)3SnS(CH2)3SSn(C6H5)3 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
Na;
palladium dichloride;
In
tetrahydrofuran;
N2; thiol (2.25 mmol) and Na (4.51 mmol) refluxed in THF for 4 h, soln. added dropwise to THF soln. of Sn compd. (2.25 mmol) at 0°C, PdCl2 added, mixt. stirred at room temp. overnight; filtered, evapd., chromd. (SiO2, hexane/CH2Cl2), recrystd. (EtOH/THF, 4°C), elem. anal.;
DOI:10.1016/j.ica.2009.05.011
- Guidance literature:
-
With
sulfur dichloride;
In
tetrahydrofuran;
for 24h;
Ambient temperature;
DOI:10.1246/cl.1980.1355
- Guidance literature:
-
In
tetrahydrofuran;
N2; Ru compd. (0.15 mmol) and Sn compd. (0.156 mmol) refluxed in THF for3 h; evapd., chromd. (SiO2, hexane/CH2Cl2=7/3), recrystd. (hexane/CH2Cl2, 4°C), elem. anal.;
DOI:10.1016/j.ica.2009.05.011
