methyl 1H-benzo[d]imidazole-4-carboxylate

Base Information

Chemical Name:methyl 1H-benzo[d]imidazole-4-carboxylate
CAS No.:37619-25-3
Molecular Formula:C9H8 N2 O2
Molecular Weight:176.175
Hs Code.:2933990090
DSSTox Substance ID:DTXSID50566262
Nikkaji Number:J3.273.708K
Wikidata:Q82451800
Mol file:37619-25-3.mol

Synonyms:methyl 1H-benzo[d]imidazole-4-carboxylate;37619-25-3;methyl 1h-benzimidazole-4-carboxylate;1H-Benzimidazole-4-carboxylic acid methyl ester;methyl 1H-benzo[d]imidazole-7-carboxylate;1H-Benzimidazole-4-carboxylic acid, methyl ester;Methyl 1,3-benzodiazole-4-carboxylate;MFCD09910212;Methyl Benzimidazole-4-carboxylate;4-methoxycarbonylbenzimidazole;SCHEMBL536589;Methyl 4-benzimidazolecarboxylate;DTXSID50566262;UZMYAXZLWVFGBD-UHFFFAOYSA-N;AMY12026;methyl 3H-benzimidazole-4-carboxylate;AKOS006239554;AKOS015900987;FS-3665;AC-29673;SY031933;methyl 1H-1,3-benzodiazole-4-carboxylate;methyl 1H-1,3-benzodiazole-7-carboxylate;Benzimidazole-7-Carboxylic Acid Methyl Ester;CS-0007685;EN300-180523;Methyl ester1H-benzimidazole-7-carboxylic acid;1H-Benzoimidazole-4-carboxylic acid methyl ester;METHYL1H-BENZO[D]IMIDAZOLE-4-CARBOXYLATE;A874056;1H-Benzimidazole-4-carboxylicacid,methylester(9CI)

Suppliers and Price of methyl 1H-benzo[d]imidazole-4-carboxylate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Usbiological
Methyl 1,3-benzodiazole-4-carboxylate
25mg
$ 305.00

TRC
Methyl1,3-Benzodiazole-4-carboxylate
500mg
$ 110.00

Oakwood
Methyl1H-benzo[d]imidazole-4-carboxylate 95+%
100mg
$ 64.00

Matrix Scientific
Methyl1H-benzo[d]imidazole-4-carboxylate 97%
10g
$ 2160.00

Matrix Scientific
Methyl1H-benzo[d]imidazole-4-carboxylate 97%
5g
$ 1342.00

Chemenu
Methyl1H-benzo[d]imidazole-4-carboxylate 98%
5g
$ 358.00

Chemenu
Methyl1H-benzo[d]imidazole-4-carboxylate 98%
1g
$ 131.00

Apolloscientific
Methyl1,3-benzodiazole-4-carboxylate 98%
250mg
$ 115.00

Apolloscientific
Methyl1,3-benzodiazole-4-carboxylate 98%
1g
$ 220.00

American Custom Chemicals Corporation
1H-BENZIMIDAZOLE-4-CARBOXYLIC ACID METHYL ESTER 95.00%
5MG
$ 500.56

Total 26 raw suppliers

Chemical Property of methyl 1H-benzo[d]imidazole-4-carboxylate

Chemical Property:

Vapor Pressure:3.9E-07mmHg at 25°C
Refractive Index:1.648
Boiling Point:416.2°Cat760mmHg
PKA:10.78±0.30(Predicted)
Flash Point:205.5°C
PSA：54.98000
Density:1.324g/cm³
LogP:1.34950
Storage Temp.:Sealed in dry,Room Temperature
XLogP3:1.3
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:2
Exact Mass:176.058577502
Heavy Atom Count:13
Complexity:208

Purity/Quality:

99%, ^*data from raw suppliers

Methyl 1,3-benzodiazole-4-carboxylate ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:COC(=O)C1=C2C(=CC=C1)NC=N2

Technology Process of methyl 1H-benzo[d]imidazole-4-carboxylate

There total 14 articles about methyl 1H-benzo[d]imidazole-4-carboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 64-18-6
formic acid

: 57113-91-4
methyl 3-nitroanthranilate

: 37619-25-3
methyl 3H-1,3-benzodiazole-4-carboxylate

Guidance literature:: With iron; ammonium chloride; In isopropyl alcohol; at 80 ℃; for 1h;
DOI:10.1055/s-0030-1259007

Reference yield: 92.0%

: 1-benzyl-1H-benzo[d]imidazole-7-carboxylic acid methyl ester

: 37619-25-3
methyl 1H-benzo[d]imidazole-4-carboxylate

Guidance literature:: With triethylsilane; palladium 10% on activated carbon; In tetrahydrofuran; at 20 ℃; for 14h; Inert atmosphere;
DOI:10.1016/j.tetlet.2015.03.127