METHYL-B-L-ARABINOPYRANOSIDE APPROX.

Base Information

• Chemical Name: METHYL-B-L-ARABINOPYRANOSIDE APPROX.
• CAS No.: 3795-69-5
• Molecular Formula: C6H12 O5
• Molecular Weight: 164.158
• Hs Code.: 29389090
• Mol file: 3795-69-5.mol

Synonyms:Arabinofuranoside,methyl, b-L- (8CI); Methyl b-L-arabinofuranoside; Methyl b-L-arabinoside

Chemical Property of METHYL-B-L-ARABINOPYRANOSIDE APPROX.

Chemical Property:

• Boiling Point: 314°Cat760mmHg
• Flash Point: 143.7°C
• PSA: 79.15000
• Density: 1.4g/cm³
• LogP: -1.92820

Purity/Quality:

99% ^*data from raw suppliers

Methylβ-L-Arabinopyranoside ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHYL-B-L-ARABINOPYRANOSIDE APPROX.

There total 34 articles about METHYL-B-L-ARABINOPYRANOSIDE APPROX. which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

methanol (67-56-1) + D-Ribose (532-20-7,613-83-2,7261-25-8,7687-39-0,13221-22-2,14795-83-6,15761-67-8,20074-49-1,25545-03-3,25545-04-4,32445-75-3,34436-17-4,36441-93-7,36468-53-8,37110-85-3,37388-49-1,38029-69-5,40461-77-6,40461-89-0,41546-19-4,41546-20-7,41546-21-8,41546-26-3,41546-29-6,41546-30-9,41546-31-0,126872-16-0,131064-98-7) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With Dowex-50 (H+); at 4 ℃;

DOI:10.1002/ejoc.200600182

Reference yield: 100.0%

methanol (67-56-1) + D-ribose (50-69-1) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With Dowex-50w (H⁺); at 0 ℃; for 24h; Inert atmosphere;

DOI:10.1016/j.bmc.2010.07.005

Reference yield: 79.0%

methanol (67-56-1) + C30H26N4O8 (189129-08-6) → methyl ribofuranoside (1824-96-0,1824-97-1,3795-68-4,3795-69-5,4229-54-3,5531-18-0,7473-45-2,13039-63-9,13039-64-0,13039-65-1,13039-67-3,22416-73-5,22861-09-2,25129-51-5,52485-92-4,52689-55-1,52689-56-2,56607-40-0,72880-70-7,79083-42-4,86782-30-1,86782-31-2,89615-03-2,89673-67-6,89707-99-3,102045-32-9,135910-17-7)

Guidance literature:

With sodium methylate; for 0.75h; Ambient temperature; other reagent, reaction time;

DOI:10.1080/07328319708002528

upstream raw materials:

methanol

L-(+)-arabinose

methyl 2,5-di-O-caffeyl-α-L-arabinofuranoside

D-lyxose

Downstream raw materials:

methyl-tri-O-methyl-arabinofuranoside

methyl 2,3-di-O-methyl-D-riboside

methyl 2,5-di-O-methyl-D-riboside

methyl 3,5-di-O-methyl-D-riboside

Refernces

• 1、 -. "BIOMARKER PANEL TARGETED TO DISEASES DUE TO MULTIFACTORIAL ONTOLOGY OF GLYCOCALYX DISRUPTION". Paragraph 0292; 0306. . Retrieved 2021/04/02.
• 2、 -. "Novel saccharide bio-based cyclic phosphorus/phosphonate as well as preparation method and application thereof". Paragraph 0039; 0041-0042. . Retrieved 2021/09/04.