5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE

Base Information

• Chemical Name: 5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE
• CAS No.: 36995-20-7
• Molecular Formula: C₄₈H₃₆ClFeN₄O₄
• Molecular Weight: 824.138
• Mol file: 36995-20-7.mol

Synonyms:Iron,chloro[5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphinato(2-)-N21,N22,N23,N24]-,(SP-5-12)-; 21H,23H-Porphine, 5,10,15,20-tetrakis(4-methoxyphenyl)-, ironcomplex; 21H,23H-Porphine, iron deriv.;5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphine iron(III) chloride;Chloro(5,10,15,20-tetrakis(4-methoxyphenyl)porphyrinato)iron;Chloro(tetra(p-methoxyphenyl)porphyrinato)iron;Chloro(tetrakis(4-methoxyphenyl)porphyrinato)iron;Chloro[5,10,15,20-tetrakis(4-methoxyphenyl)porphinato]iron;[5,10,15,20-Tetrakis(p-methoxyphenyl)porphinato]iron(III) chloride

Chemical Property of 5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE

Chemical Property:

• Melting Point: 300 °C (methanol)
• PSA: 71.50000
• LogP: 7.15920

Purity/Quality:

98%,99%, ^*data from raw suppliers

Fe(III)meso-Tetra(4-methoxyphenyl)porphineChloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Uses: Fe(III) meso-Tetra(4-methoxyphenyl) porphine chloride is a useful catalyst for organic and organometallic reactions. FeTMPPCI may be used to form interfacial molecular assemblies of metalloporphyrins. It has been used in the delignification of wood chips and pulps.

Technology Process of 5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE

There total 8 articles about 5,10,15,20-TETRAKIS(4-METHOXYPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.2%

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin (22112-78-3) → (5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine)iron(III) chloride (333460-15-4,36995-20-7)

Guidance literature:

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin; With iron(II) chloride tetrahydrate; In N,N-dimethyl-formamide; for 0.5h;

With hydrogenchloride; In water; at 50 - 60 ℃;

DOI:10.3390/molecules16042960

Reference yield: 95.2%

iron(II) chloride tetrahydrate + 5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin (22112-78-3) → (5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine)iron(III) chloride (333460-15-4,36995-20-7)

Guidance literature:

In N,N-dimethyl-formamide; for 0.5h; Reflux;

DOI:10.1021/op060056z

Reference yield: 90.0%

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin (22112-78-3) + iron(II) chloride → (5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine)iron(III) chloride (333460-15-4,36995-20-7)

Guidance literature:

5,10,15,20-tetrakis(4-methoxyphenyl)porphyrin; iron(II) chloride; In tetrahydrofuran; for 20h; Reflux; Inert atmosphere; Darkness;

With air; In tetrahydrofuran; at 20 ℃; for 0.333333h; Darkness;

DOI:10.1016/j.tet.2016.01.013

upstream raw materials:

iron(III) chloride

{(p-OMeTPP)Fe}2O

pyrrole

4-methoxy-benzaldehyde

Downstream raw materials:

chloride

iron(III)

5,10,15,20-tetrakis(4-methoxylphenyl)porphyrinate iron(II)

C₄₈H₃₇FeN₄O₄S