METHY BENZYL BUTANEDIOIC ACID

Base Information

• Chemical Name: METHY BENZYL BUTANEDIOIC ACID
• CAS No.: 35262-43-2
• Molecular Formula: C13H16 O4
• Molecular Weight: 236.268
• Hs Code.: 2917399090
• Mol file: 35262-43-2.mol

Synonyms:Butanedioicacid, (phenylmethyl)-, dimethyl ester (9CI); Succinic acid, benzyl-, dimethylester (6CI); (?à)-Dimethylbenzylsuccinate; DL-Dimethyl benzylsuccinate; dl-Dimethyl benzylsuccinate

Chemical Property of METHY BENZYL BUTANEDIOIC ACID

Chemical Property:

• Boiling Point: 159 °C(Press: 1 Torr)
• PSA: 52.60000
• Density: 1.113±0.06 g/cm3(Predicted)
• LogP: 1.58140

Purity/Quality:

99% ^*data from raw suppliers

METHYL BENZYL BUTANEDIOIC ACID 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of METHY BENZYL BUTANEDIOIC ACID

There total 40 articles about METHY BENZYL BUTANEDIOIC ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

phenylzinc chloride (28557-00-8) + Dimethyl itakonate (617-52-7) → dimethyl 2-benzylsuccinate (35262-43-2)

Guidance literature:

With chloro-trimethyl-silane; [Rh(η⁶-C6H5F){PCyp2(η²-C5H7)}][BAr^F₄]; In tetrahydrofuran; at 20 ℃; for 2h;

DOI:10.1039/b608129k

Reference yield: 94.0%

benzyl bromide (100-39-0) + dimethylfumarate (624-49-7) → dimethyl 2-benzylsuccinate (35262-43-2)

Guidance literature:

With 2,6-dimethylpyridine; crithmene; potassium 5-bromo-1H-indole-1-carbodithioate; In acetonitrile; at 60 ℃; for 24h; Irradiation;

DOI:10.1038/s41557-018-0173-x

Reference yield: 91.0%

benzyl mesylate (55791-06-5) + dimethylfumarate (624-49-7) → dimethyl 2-benzylsuccinate (35262-43-2)

Guidance literature:

With 2,6-dimethylpyridine; crithmene; potassium 5-bromo-1H-indole-1-carbodithioate; In acetonitrile; at 60 ℃; for 24h; Irradiation;

DOI:10.1038/s41557-018-0173-x

upstream raw materials:

methanol

2-benzylsuccinic acid

dimethyl cis-but-2-ene-1,4-dioate

benzylmagnesium chloride

Downstream raw materials:

2-benzylsuccinic acid

(S)-3-benzyl-4-methoxy-4-oxobutanoic acid

dimethyl (R)-(+)-benzylsuccinate

3-benzyldihydrofuran-2,5-dione