tris(benzenethiolato)indium(III)

Base Information

• Chemical Name: tris(benzenethiolato)indium(III)
• CAS No.: 1046154-90-8
• Molecular Formula: C₁₈H₁₅InS₃
• Molecular Weight: 442.335
• Mol file: 1046154-90-8.mol

Synonyms:tris(benzenethiolato)indium(III)

Chemical Property of tris(benzenethiolato)indium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

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Technology Process of tris(benzenethiolato)indium(III)

There total 7 articles about tris(benzenethiolato)indium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

indium(III) chloride (10025-82-8) + thiophenol (108-98-5) → tris(benzenethiolato)indium(III) (1046154-90-8)

Guidance literature:

In benzene; molar ratio In/Si: 1:3, N2 atmosphere, refluxed, 6 h, pptn.; ppt. extd. with ether, washed with pentane, dried in vacuum, elem. anal.;

DOI:10.1016/0022-328X(88)80004-4

Reference yield: 95.0%

indium (7440-74-6) + diphenyldisulfane (882-33-7) → tris(benzenethiolato)indium(III) (1046154-90-8)

Guidance literature:

In methanol; other Radiation; solvothermal synthesis; heating PhSSPh and In powder (1.5:1 mol) in MeOHsoln. at 120°C for 15 min with microwave irradn.; evapd. (vac.); elem. anal.; TGA;

DOI:10.1016/j.inoche.2010.11.010

Reference yield: 60.0%

sodium thiophenolate (930-69-8) + indium(III) chloride (10025-82-8) → tris(benzenethiolato)indium(III) (1046154-90-8)

Guidance literature:

In methanol; byproducts: NaCl; sol. of NaSPh in methanol was added dropwise over 1 h to a refluxing solution of InCl3 in methanol; filtration, filtrate was taken to dryness in vacuo, dissolved in benzenesolid recrystd. from n-pentane; elem.anal., NMR;

upstream raw materials:

sodium thiophenolate

indium(III) chloride

indium

1,1-dimethylpropanethiol

Downstream raw materials:

tris(benzenethiolato)indium(III)-bis-pyridine

(C₆H₅S)3In(tricyclohexylphosphine)

(C₆H₅S)3In(triethylphosphine)

(C₆H₅S)3In(triphenylphosphine)

Refernces

• 1、 Peppe, Clovis,Borges De Castro, Lierson. "On the reactivity of indium(III) benzenechalcogenolates (chalcogen = sulfur and selenium) towards organyl halides for the synthesis of organyl phenyl chalcogenides". . p. 678 - 683. Retrieved 2009/10/30.
• 2、 Green, James H.,Kumar, Rajesh,Seudeal, Narace,Tuck, Dennis G.. "Direct electrochemical synthesis of alkane- and arenethiolato derivatives of indium and thallium". . p. 123 - 127. Retrieved 2008/10/08.