Ir(ttp)C₆D₆

Base Information

• Chemical Name: Ir(ttp)C₆D₆
• CAS No.: 1280227-68-0
• Molecular Formula: C₅₄H₄₁IrN₄
• Molecular Weight: 943.127
• Mol file: 1280227-68-0.mol

Synonyms:Ir(ttp)C₆D₆

Chemical Property of Ir(ttp)C₆D₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ir(ttp)C₆D₆

There total 3 articles about Ir(ttp)C₆D₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 12.0%

benzene-d6 (1076-43-3) + (p-fluorophenyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1280227-56-6) → fluorobenzene (462-06-6) + phenyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1224699-27-7) + Ir(ttp)C6D6 (1280227-68-0)

Guidance literature:

With potassium hydroxide; In neat (no solvent); at 200 ℃; for 96h; Inert atmosphere;

DOI:10.1021/om5005594

Reference yield:

benzene-d6 (1076-43-3) + β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1319720-88-1) → Ir(ttp)C6D6 (1280227-68-0) + (μ-oxo)bis((aqua)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III))

Guidance literature:

With water; at 120 ℃; for 552h; Darkness;

DOI:10.1021/om200251k

Reference yield:

benzene-d6 (1076-43-3) + β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III) (1319720-88-1) + water (7732-18-5) → Ir(ttp)C6D6 (1280227-68-0) + (μ-oxo)bis((aqua)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III))

Guidance literature:

In benzene-d6; byproducts: C2H4; Ir-complex and C6D6 were sealed under vac. in NMR tube, heated at 120°C for 23 days; detected by NMR spectra;

DOI:10.1021/om200251k

upstream raw materials:

benzene-d6

β-hydroxyethyl(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)

water

(p-fluorophenyl)(5,10,15,20-tetrakis(p-tolyl)porphyrinato)iridium(III)