tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane

Base Information

• Chemical Name: tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane
• CAS No.: 74559-43-6
• Molecular Formula: C₄H₁₀O₂*C₃₆H₉₉PrSi₉Sn₃
• Molecular Weight: 1372.11
• Mol file: 74559-43-6.mol

Synonyms:tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane

Chemical Property of tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane

There total 1 articles about tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.2%

Tris<(trimethylsilyl)-methyl>stannan (34501-61-6) + tris(bis(trimethylsilyl)amido)praseodymium(III) → tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane (74559-43-6) + 1,1,1,3,3,3-hexamethyl-disilazane (999-97-3)

Guidance literature:

In 1,2-dimethoxyethane; (vac.) to soln. of Pr compd. was added tin compd. and mixt. was heated at 100°C for 15 h; solvent was removed in vac., residue washed with hexane and dried in vac.; elem. anal.; (Me3Si)2NH was detected by GLC anal. of volatiles;

DOI:10.1016/S0022-328X(00)85913-6

Reference yield: 98.4%

tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane (74559-43-6) + dibenzoyl peroxide (94-36-0) → ((CH3)3SiCH2)3SnPr(OCOC6H5)2 + ((CH3)3SiCH2)3Sn(OCOC6H5) (42202-20-0)

Guidance literature:

In benzene; soln. of Pr-Sn complex was shaken with soln. of benzoylperoxide at 50°C for 12 h; Sn-Pr complex pptd.; elem. anal.; org. layer was sepd. by distn.;

DOI:10.1016/S0022-328X(00)85913-6

Reference yield: 95.7%

tris[tris(trimethylsilylmethyl)stannyl]praseodymium*1,2-dimethoxyethane (74559-43-6) → methane (34557-54-5,27936-85-2) + hydrogen (1333-74-0) + praseodymium(III) chloride (10361-79-2) + Chlor-tris<(trimethylsilyl)methyl>zinn (34570-67-7)

Guidance literature:

With hydrogenchloride; In tetrahydrofuran; soln. of Pr compd. and dry HCl (1:6 mol) was shaken for 1 h at room temp.; formed ppt. of PrCl3 was filtered off, washed with THF and dried; org. layer was sepd. by distn in vac.;

DOI:10.1016/S0022-328X(00)85913-6

upstream raw materials:

Tris<(trimethylsilyl)-methyl>stannan

Downstream raw materials:

hydrogen

praseodymium(III) chloride

Methyl-tris<(trimethylsilyl)methyl>zinn

Chlor-tris<(trimethylsilyl)methyl>zinn