<3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Base Information

Chemical Name:<3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole
CAS No.:89755-56-6
Molecular Formula:C₁₇H₂₂O₄
Molecular Weight:290.359
Hs Code.:

Synonyms:<3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Suppliers and Price of <3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of <3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Chemical Property:

Boiling Point:365.8±42.0 °C(Predicted)
Density:1.13±0.1 g/cm3(Predicted)

Purity/Quality:: 95-333%min ^*data from raw suppliers

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Technology Process of <3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

There total 11 articles about <3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 546141-37-1
(3aR,5R,6S,6aR)-5-allyl-2,2-dimethyl-3a,5,6,6a-tetrahydrofuro[2,3-d][1,3]dioxol-6-ol

: 100-39-0
benzyl bromide

: 89755-56-6
<3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Guidance literature:: With potassium tert-butylate; In tetrahydrofuran; at -10 ℃;
DOI:10.1055/s-0032-1317920

Reference yield:

: 41670-98-8,70632-46-1
1-((3aR,6R,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-ethanone

: 762-72-1
allyl-trimethyl-silane

: 120417-92-7
(3aR,5S,6S,6aR)-5-Allyl-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxole

: 89755-56-6
<3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Guidance literature:: With magnesium bromide; In dichloromethane; at 15 ℃; for 15h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
DOI:10.1016/S0040-4039(00)82295-9

Reference yield:

: 39682-04-7
(3aR,5S,6R,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuran[2,3-d][1,3]dioxolane-5-carboxylic acid

: 89755-56-6
<3aR(3aα,5β,6β,6aα)>-tetrahydro-2,2-dimethyl-5-(2-propen-1-yl)-6-(phenylmethoxy)furo<2,3-d>-1,3-dioxole

Guidance literature:: Multi-step reaction with 2 steps

1: 81 percent / pyridine / acetonitrile / 5 h / 20 °C / α/β ratio= 72/28

2: MgBr₂ / CH₂Cl₂ / 15 h / 15 °C

With pyridine; magnesium bromide; In dichloromethane; acetonitrile;
DOI:10.1016/S0040-4039(00)82295-9