Benzoic acid, ethyl ester, radical ion(1+) (9CI)

Base Information

• Chemical Name: Benzoic acid, ethyl ester, radical ion(1+) (9CI)
• CAS No.: 99341-95-4
• Molecular Formula: C₉H₁₀O₂
• Molecular Weight: 150.177
• Mol file: 99341-95-4.mol

Synonyms:Benzoic acid, ethyl ester, radical ion(1-) (9CI)

Chemical Property of Benzoic acid, ethyl ester, radical ion(1+) (9CI)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Benzoic acid, ethyl ester, radical ion(1+) (9CI)

There total 975 articles about Benzoic acid, ethyl ester, radical ion(1+) (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

ethanol (64-17-5) + benzo[d]isoxazol-3-yl(phenyl)methanone (60451-91-4) → salicylonitrile (611-20-1) + benzoic acid ethyl ester (93-89-0,99341-95-4)

Guidance literature:

With potassium hydroxide; for 16h; Ambient temperature;

Reference yield: 91.0%

2-hydroxy-2-phenylacetophenone (119-53-9,579-44-2) → benzoic acid ethyl ester (93-89-0,99341-95-4) + benzaldehyde (100-52-7)

Guidance literature:

With oxygen; H₅PV₂Mo₁₀O₄₀(1,11); In ethanol; at 20 ℃; for 6h; under 750.06 Torr;

DOI:10.1039/C39890000825

Reference yield: 34.0%

2-phenyl-3-(benzyloxy)propan-1-ol (189886-53-1) → (RS)-2-phenyl-1-propanol (1123-85-9) + benzoic acid ethyl ester (93-89-0,99341-95-4) + benzyl alcohol (100-51-6,185532-71-2)

Guidance literature:

With dichloro(benzene)ruthenium(II) dimer; N,N-diisopropylimidazolium bromide; sodium hydride; In toluene; acetonitrile; for 24h; Reflux;

DOI:10.1021/ol3009842

upstream raw materials:

tetrahydrofuran

sodium acetate

4-(ethoxycarbonyl)benzenediazonium chloride

piperidine

Downstream raw materials:

1,3,5-triphenylpenta-1,4-diyn-3-ol

1-cyclopropyl-3-phenyl-1,3-propanedione

3-phenylpentan-3-ol

N-(2-cyano-1-methyl-vinyl)-benzamide

Refernces

• 1、 Yuan, Lin,Hu, Yancheng,Zhao, Zhitong,Li, Guangyi,Wang, Aiqin,Cong, Yu,Wang, Feng,Zhang, Tao,Li, Ning. "Production of Copolyester Monomers from Plant-Based Acrylate and Acetaldehyde". supporting information. . Retrieved 2021/12/14.
• 2、 Dai, Huiguang,Guan, Hairong,Krause, Jeanette A.,Li, Weishi. "Experimental Evidence of syn H-N-Fe-H Configurational Requirement for Iron-Based Bifunctional Hydrogenation Catalysts". . p. 6521 - 6535. Retrieved 2021/05/31.