(pentamethylcyclopentadienyl)2ZrH₂

Base Information

• Chemical Name: (pentamethylcyclopentadienyl)2ZrH₂
• CAS No.: 61396-34-7
• Molecular Formula: C₂₀H₃₂Zr
• Molecular Weight: 363.698
• Mol file: 61396-34-7.mol

Synonyms:(pentamethylcyclopentadienyl)2ZrH₂

Chemical Property of (pentamethylcyclopentadienyl)2ZrH₂

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (pentamethylcyclopentadienyl)2ZrH₂

There total 2 articles about (pentamethylcyclopentadienyl)2ZrH₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(η5-pentamethylcyclopentadienyl)2(zirconium)(H)(iosbutyl)2 (67108-86-5) → (pentamethylcyclopentadienyl)2ZrH2 (61396-34-7) + Cp'2Zr(H)Ph (112532-20-4)

Guidance literature:

With benzene; In benzene; Thermolysis at 75-80°C, 22 h; NMR;

Reference yield:

(pentamethylcyclopentadienyl)2Zr(C6H4F)H (383862-18-8) + hydrogen (1333-74-0) → (pentamethylcyclopentadienyl)2Zr(C6H5)F (383862-20-2) + (pentamethylcyclopentadienyl)2ZrH2 (61396-34-7)

Guidance literature:

In not given; byproducts: fluorobenzene; heating of Zr complex in the presence of H2;

DOI:10.1021/ja016087l

Reference yield: 95.0%

(pentamethylcyclopentadienyl)2ZrH2 (61396-34-7) + bis(pentafluorophenyl)borohydride (165612-94-2) → Cp(*)2ZrH(μ-H)2B(C6F5)2 (914809-08-8)

Guidance literature:

In toluene; (inert atmosphere); Zr complex added to a suspn. of HB(C6F5)2 at room temp.; evapd. (vac.); elem. anal.;

DOI:10.1021/om0604730

upstream raw materials:

(η5-pentamethylcyclopentadienyl)2(zirconium)(H)(iosbutyl)2

(pentamethylcyclopentadienyl)2Zr(C₆H₄F)H

hydrogen

Downstream raw materials:

Cp'2Zr(H)Ph

(η(5)-C5Me5)2Zr(OPh)2

(pentamethylcyclopentadienyl)(π-η(5):σ-η(1)-tetramethylfulvene)phenylzirconium

Cp'2Zr(OC₆F₅)2