3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene

Base Information

• Chemical Name: 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene
• CAS No.: 219744-38-4
• Molecular Formula: C₃₈H₄₄O₆
• Molecular Weight: 596.764
• Mol file: 219744-38-4.mol

Synonyms:3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene

Chemical Property of 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene

There total 2 articles about 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

2-chloromethyl-3-chloroprop-1-ene (1871-57-4) + dibenzyl glycerol (6972-79-8) → 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene (219744-38-4)

Guidance literature:

With sodium hydride; In tetrahydrofuran;

DOI:10.1021/ja983229b

Reference yield:

benzyl alcohol (100-51-6,185532-71-2) → 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene (219744-38-4)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. KOH, Bu₄NI

2: 95 percent / NaH / tetrahydrofuran

With potassium hydroxide; tetra-(n-butyl)ammonium iodide; sodium hydride; In tetrahydrofuran;

DOI:10.1021/ja983229b

Reference yield: 90.0%

3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene (219744-38-4) → 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propanol (219744-39-5)

Guidance literature:

3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propene; With 9-borabicyclo[3.3.1]nonane dimer; In tetrahydrofuran; at 0 ℃; for 2h;

With sodium hydroxide; dihydrogen peroxide; In tetrahydrofuran; at 20 ℃; for 1h;

DOI:10.1021/ja001903v

upstream raw materials:

2-chloromethyl-3-chloroprop-1-ene

dibenzyl glycerol

benzyl alcohol

Downstream raw materials:

3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propanol

dioctadecylcarbamic acid 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(1-benzyloxymethyl-2-benzyloxyethoxymethyl)propyl ester

({[(dioctadecylcarbamoylmethylcarbamoyl)methyl]carbamoyl}methyl)carbamic acid 3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(1-benzyloxymethyl-2-benzyloxyethoxymethyl)propyl ester

3-[3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propoxy]-2-[3-(2-benzyloxy-1-(benzyloxymethyl)ethoxy)-2-(2-benzyloxy-1-(benzyloxymethyl)ethoxymethyl)propoxymethyl]propene