methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate

Base Information

Chemical Name:methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate
CAS No.:97906-41-7
Molecular Formula:C₂₁H₃₂O₃
Molecular Weight:332.483
Hs Code.:

Synonyms:methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate

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Chemical Property of methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate

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Technology Process of methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate

There total 38 articles about methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

: 67-56-1
methanol

: 92830-65-4,110715-77-0
(E)-3-{(1R,2R)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexyl}-acrylic acid

: 90122-64-8,92935-97-2,97906-41-7,110715-78-1
(E)-3-{(1R,2R)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexyl}-acrylic acid methyl ester

Guidance literature:: With sulfuric acid;
DOI:10.1016/S0040-4039(01)91019-6

Reference yield: 47.0%

: 5927-18-4
trimethyl phosphonoacetate

: 97855-75-9
(1S,2S)-1,3,3-Trimethyl-2-[2-(2-oxo-cyclohex-3-enyl)-ethyl]-cyclohexanecarbaldehyde

: 97906-41-7
methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate

Guidance literature:: With sodium hydride; In 1,2-dimethoxyethane;
DOI:10.1016/S0040-4039(00)98546-0

Reference yield:

: 60134-39-6
(-)-(4aS,8aS)-3,4,4a,5,6,7,8,8a-octahydro-5,5,8a-trimethylnaphthalen-1(2H)-one

: 97906-41-7
methyl (1'S,2'S)-3-<1',3',3'-trimethyl-2'-<2-(2-oxocyclohex-3-enyl)ethyl>cyclohexyl>prop-2(E)-enoate

Guidance literature:: Multi-step reaction with 15 steps

1: 97 percent / PBB / acetic acid / 2 h / Ambient temperature

2: 97 percent / sodium hydroxide / dimethylformamide; H₂O / 0.5 h / Ambient temperature

3: lead tetra-acetate (LTA) / benzene / 0.17 h / Ambient temperature

4: NaBH₄ / methanol / 0.33 h / Ambient temperature

5: 98 percent / tributylphosphine / tetrahydrofuran / 0.33 h / Ambient temperature

6: 91 percent / hydrogen peroxide / tetrahydrofuran / 10 h / Ambient temperature

7: 1.) lithium aluminium hydride; 2.) sodium hydroxide / 1.) diethyl ether, rt, 30 min; 2.) water, 30 min.

8: 88 percent / Florisil, PCC / CH₂Cl₂ / 1 h / Ambient temperature

9: 98 percent / toluene-p-sulphonic acid / benzene / 0.33 h / Heating

10: 1. osmium tetraoxide; 2.) sodium periodate / 1.) diethyl ether, water, rt, 5 min; 2.) rt, 10 h.

11: 1.) lithium diisopropylamide (LDA) / 1.) THF, -78 deg C; 2.) THF, rt, 1 h.

12: 98 percent / H₂ / 10 percent palladium-charcoal / ethanol

14: 83 percent / 10 percent perchloric acid / tetrahydrofuran / 1 h / Ambient temperature

15: 47 percent / NaH / 1,2-dimethoxy-ethane / 72 h / Ambient temperature

With lead(IV) acetate; sodium hydroxide; sodium tetrahydroborate; florisil; sodium periodate; osmium(VIII) oxide; lithium aluminium tetrahydride; perchloric acid; tributylphosphine; hydrogen; dihydrogen peroxide; sodium hydride; toluene-4-sulfonic acid; pyridinium chlorochromate; lithium diisopropyl amide; palladium on activated charcoal; In tetrahydrofuran; methanol; 1,2-dimethoxyethane; ethanol; dichloromethane; water; acetic acid; N,N-dimethyl-formamide; benzene;