Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

Base Information

Chemical Name:Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate
CAS No.:308804-97-9
Molecular Formula:C₃₃H₃₁NO₁₁
Molecular Weight:617.609
Hs Code.:

Synonyms:Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

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Chemical Property of Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

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Technology Process of Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

There total 8 articles about Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 393-85-1
methyl 5-fluoro-2-nitrobenzoate

: 308804-96-8
Methyl 3-{4-[2-(2-hydroxy-3,6-dimethoxyphenyl)ethyl]phenoxy}-4-methoxybenzoate

: 308804-97-9
Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 90 ℃; for 24h;
DOI:10.1055/s-2000-7106

Reference yield:

: 64466-51-9
3,6-Dimethoxy-2-hydroxybenzaldehyde

: 308804-97-9
Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

Guidance literature:: Multi-step reaction with 4 steps

1: 60 percent / K₂CO₃ / methanol / Heating

2: 76 percent / K₂CO₃; 18-crown-6 / toluene / 24 h / Heating

3: 84 percent / H₂ / 5 percent Pd/C / ethyl acetate / 24 h / 20 °C / 2250.18 - 3750.3 Torr

4: 99 percent / K₂CO₃ / dimethylformamide / 24 h / 90 °C

With 18-crown-6 ether; hydrogen; potassium carbonate; palladium on activated charcoal; In methanol; ethyl acetate; N,N-dimethyl-formamide; toluene; 1: Etherification / 2: Condensation / 3: Hydrogenation / 4: Etherification;
DOI:10.1055/s-2000-7106

Reference yield:

: 135303-87-6
methyl 3-(4'-formylphenoxy)-4-methoxybenzoate

: 308804-97-9
Methyl 3-(4-{2-[3,6-dimethoxy-2-(3-methyloxycarbonyl-4-nitrophenoxy)phenyl]ethyl}phenoxy)-4-methoxybenzoate

Guidance literature:: Multi-step reaction with 6 steps

1: 100 percent / NaBH₄ / methanol / 20 °C

2: 91 percent / SOCl₂; pyridine / diethyl ether / 4 h / Heating

3: 85 percent / toluene / 24 h / Heating

4: 76 percent / K₂CO₃; 18-crown-6 / toluene / 24 h / Heating

5: 84 percent / H₂ / 5 percent Pd/C / ethyl acetate / 24 h / 20 °C / 2250.18 - 3750.3 Torr

6: 99 percent / K₂CO₃ / dimethylformamide / 24 h / 90 °C

With pyridine; sodium tetrahydroborate; thionyl chloride; 18-crown-6 ether; hydrogen; potassium carbonate; palladium on activated charcoal; In methanol; diethyl ether; ethyl acetate; N,N-dimethyl-formamide; toluene; 1: Reduction / 2: Substitution / 3: Substitution / 4: Condensation / 5: Hydrogenation / 6: Etherification;
DOI:10.1055/s-2000-7106