2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole

Base Information

• Chemical Name: 2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole
• CAS No.: 947342-79-2
• Molecular Formula: C₃₅H₃₆N₂O
• Molecular Weight: 500.684
• Mol file: 947342-79-2.mol

Synonyms:2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole

Chemical Property of 2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole

There total 1 articles about 2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

3,5-di-tert-butyl-2-hydroxybenzaldehyde (37942-07-7) + aniline (62-53-3) + benzil (134-81-6) → 2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole (947342-79-2)

Guidance literature:

With ammonium acetate; In acetic acid; at 110 ℃; for 12h;

DOI:10.1016/j.jorganchem.2007.04.010

Reference yield: 61.0%

2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole (947342-79-2) + dichloromethane (75-09-2) + copper(ll) bromide (7789-45-9) → bis[(2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole)]copper(II)*2(dichloromethane)

Guidance literature:

With butyllithium; In tetrahydrofuran; hexane; dichloromethane; (under N2, Schlenk); soln. of butyllithium in hexane added to soln. of ligand in THF, stirred for 2 h, added dropwise to suspn. of CuBr2 in CH2Cl2, stirred for 6 h at room temp.; dried in vacuo, residue extd. with CH2Cl2, recrystd. from CH2Cl2/hexane at room temp.; elem. anal.;

DOI:10.1016/j.jorganchem.2007.04.010

Reference yield: 46.0%

2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole (947342-79-2) + dichloromethane (75-09-2) + nickel dichloride (83864-14-6) → bis[(2'-(4',6'-di-tert-butylhydroxyphenyl)-1,4,5-triphenyl imidazole)]nickel(II)*2(dichloromethane)

Guidance literature:

With butyllithium; In tetrahydrofuran; hexane; dichloromethane; (under N2, Schlenk); soln. of butyllithium in hexane added to soln. of ligand in THF, stirred for 2 h, added dropwise to suspn. of NiCl2 in CH2Cl2, stirred for 6 h at room temp.; dried in vacuo, residue extd. with CH2Cl2, recrystd. from CH2Cl2/hexane at room temp.; elem. anal.;

DOI:10.1016/j.jorganchem.2007.04.010

upstream raw materials:

3,5-di-tert-butyl-2-hydroxybenzaldehyde

aniline

benzil