(4-Bromophenylthio)dimethyl-tert-butylsilane

Base Information

Chemical Name:(4-Bromophenylthio)dimethyl-tert-butylsilane
CAS No.:153312-70-0
Molecular Formula:C12H19 Br S Si
Molecular Weight:303.338
Hs Code.:
European Community (EC) Number:622-838-1
DSSTox Substance ID:DTXSID70448571
Nikkaji Number:J1.117.634H
Wikidata:Q82267626
Mol file:153312-70-0.mol

Synonyms:(4-Bromophenylthio)dimethyl-tert-butylsilane;153312-70-0;(4-bromophenyl)sulfanyl-tert-butyl-dimethylsilane;(4-Bromophenylthio)-dimethyl-tert-butylsilane;DTXSID70448571;AKOS015898385;tert-Butyldimethyl[(4-bromophenyl)thio]silane;(4-Bromophenylthio)dimethyl-tert-butylsilane, 97%

Suppliers and Price of (4-Bromophenylthio)dimethyl-tert-butylsilane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of (4-Bromophenylthio)dimethyl-tert-butylsilane

Chemical Property:

Vapor Pressure:0.001mmHg at 25°C
Melting Point:42-44 °C(lit.)
Refractive Index:1.54
Boiling Point:120-130 °C0.2-0.3 mm Hg(lit.)
Flash Point:>230 °F
PSA：25.30000
Density:1.205g/cm³
LogP:5.54640
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:302.01601
Heavy Atom Count:15
Complexity:202

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36/37/38
Safety Statements: 26-36/37

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)[Si](C)(C)SC1=CC=C(C=C1)Br

Technology Process of (4-Bromophenylthio)dimethyl-tert-butylsilane

There total 1 articles about (4-Bromophenylthio)dimethyl-tert-butylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 18162-48-6
tert-butyldimethylsilyl chloride

: 106-53-6
para-bromobenzenethiol

: 153312-70-0
(4-bromophenylsulfanyl)-tert-butyldimethylsilane

Guidance literature:: With sodium hydride; In tetrahydrofuran; at 20 ℃; for 14h;
DOI:10.1016/S0022-328X(99)00086-8

Reference yield: 88.0%

: 558-63-4
di-tert-butyldifluorosilane

: 153312-70-0
(4-bromophenylsulfanyl)-tert-butyldimethylsilane

: 1112840-19-3
1-(tert-butyldimethylsilanylsulfanyl)-4-(di-tert-butylfluorosilanyl)benzene

Guidance literature:: (4-bromophenylsulfanyl)-tert-butyldimethylsilane; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.416667h; Inert atmosphere;

di-tert-butyldifluorosilane; In diethyl ether; pentane; at -78 - 20 ℃; for 24h; Inert atmosphere;
DOI:10.1055/s-0037-1611656

Reference yield: 83.0%

: 558-63-4
di-tert-butyldifluorosilane

: 153312-70-0
(4-bromophenylsulfanyl)-tert-butyldimethylsilane

: 1196878-31-5
di-tert-butylfluorophenylsulfanylsilane

: 1112840-19-3
1-(tert-butyldimethylsilanylsulfanyl)-4-(di-tert-butylfluorosilanyl)benzene

Guidance literature:: (4-bromophenylsulfanyl)-tert-butyldimethylsilane; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.5h;

di-tert-butyldifluorosilane; In diethyl ether; pentane; at -78 - 20 ℃;
DOI:10.1002/chem.200802266