Copper(II) formate tetrahydrate

Base Information

• Chemical Name: Copper(II) formate tetrahydrate
• CAS No.: 5893-61-8
• Molecular Formula: 2CHO₂*Cu*4H₂O
• Molecular Weight: 225.643
• UNII: V7RA28204J
• DSSTox Substance ID: DTXSID40207672
• Wikidata: Q27291641
• Mol file: 5893-61-8.mol

Synonyms:COPPER(II) FORMATE TETRAHYDRATE;5893-61-8;Cupric formate tetrahydrate;copper diformate tetrahydrate;Copper(2+) formate tetrahydrate;copper;diformate;tetrahydrate;Cupric formate tetrahydrate [MI];Copper formate (cu(hcoo)2) tetrahydrate;UNII-V7RA28204J;Formic acid copper salt (2:1) tetrahydrate;Copper formate tetrahydrate (cu(hcoo)2.4H2o);V7RA28204J;Copper (II) formate tetrahydrate;Copper(ii)formate tetrahydrate;Copper(II) formate 4-hydrate;DTXSID40207672;LSIWWRSSSOYIMS-UHFFFAOYSA-L;COPPER(II)FORMATETETRAHYDRATE;AKOS025295499;Formic acid, copper(2) salt, tetrahydrate;Q27291641

Chemical Property of Copper(II) formate tetrahydrate

Chemical Property:

• Melting Point: 130 °C (decomp)
• PSA: 117.18000
• Density: 1.810
• LogP: -2.25570
• Storage Temp.: Inert atmosphere,Room Temperature
• Water Solubility.: Soluble in water (125 g/L at 20°C). Very slightly soluble in alcohol. Practically insoluble in most organic solvents.
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 224.967164
• Heavy Atom Count: 11
• Complexity: 7.5

Purity/Quality:

99%, ^*data from raw suppliers

Copper(II)formatetetrahydrate 98% ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(=O)[O-].C(=O)[O-].O.O.O.O.[Cu+2]
• Uses: It is employed as an antibacterial agent in the treatment of cellulose.

Technology Process of Copper(II) formate tetrahydrate

There total 14 articles about Copper(II) formate tetrahydrate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formic acid (64-18-6) + copper(II) nitrate trihydrate + water (7732-18-5) → copper(II) formate dihydrate (5893-61-8,14690-98-3,15305-21-2,16842-73-2,22992-79-6,34729-06-1,133386-02-4,133386-04-6)

Guidance literature:

at 50 ℃; Temperature;

DOI:10.1016/j.jallcom.2020.156208

Reference yield:

formic acid (64-18-6) + copper(II) nitrate trihydrate + water (7732-18-5) → copper(II) formate tetrahydrate (5893-61-8,14690-98-3,15305-21-2,16842-73-2,22992-79-6,34729-06-1,133386-02-4,133386-04-6)

Guidance literature:

at 50 ℃; Temperature;

DOI:10.1016/j.jallcom.2020.156208

Reference yield:

→ copper(II) formate dihydrate (5893-61-8,14690-98-3,15305-21-2,16842-73-2,22992-79-6,34729-06-1,133386-02-4,133386-04-6)

Guidance literature:

With water; at 50 - 60 ℃;

upstream raw materials:

formic acid

copper hydroxide

water

ethanol

Downstream raw materials:

copper(II) formate

copper(II) formate dihydrate

copper 8-hydroxyquinolinate

[Cu2(μ-formate)4(2-(phenylamino)pyridine)2]

Refernces

• 1、 Tajiri,Matsumoto,Deguchi,Mito,Takagi,Moriyoshi,Itoh,Koyama. "Effect of pressure on two-dimensional Heisenberg antiferromagnet Cu(HCOO)2·4H2O". . p. e566-e568. Retrieved 2008/10/09.
• 2、 Stoilova,Koleva. "IR study of dibarium copper formate tetrahydrate". . p. 291 - 295. Retrieved 2007/10/03.