Isopropylcyclopentadienyltitaniumtrichloride

Base Information

Chemical Name:Isopropylcyclopentadienyltitaniumtrichloride
CAS No.:69276-78-4
Molecular Formula:C8H12Cl3Ti-2
Molecular Weight:261.414
Hs Code.:
Mol file:69276-78-4.mol

Synonyms:Isopropylcyclopentadienyltitaniumtrichloride

Suppliers and Price of Isopropylcyclopentadienyltitaniumtrichloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of Isopropylcyclopentadienyltitaniumtrichloride

Chemical Property:

PSA：0.00000
LogP:-6.45180

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of Isopropylcyclopentadienyltitaniumtrichloride

There total 1 articles about Isopropylcyclopentadienyltitaniumtrichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 12130-65-3
bis(isopropylcyclopentadienyl)titanium dichloride

: 7550-45-0
titanium tetrachloride

: 69276-78-4
η5-isopropylcyclopentadienyl titanium trichloride

Guidance literature:: In neat (no solvent); mixt. sealed in a glass tube under vac., heated to 120°C for 60 h; tube cooled, opened under an inert gas atmosphere; solid washed with hexane to remove unreacted TiCl4, sublimed at 60°C (0.03 Torr); elem. anal.;
DOI:10.1021/ja00209a023

Reference yield: 80.0%

: 69276-78-4
η5-isopropylcyclopentadienyl titanium trichloride

: 2216-51-5
(-)-menthol

: [(C₅H₄CH(CH₃)2)Cl₂(1R,3R,4S-mentholate)titanium(IV)]

Guidance literature:: With triethylamine; In benzene; Ar, to a soln. of Ti compd. gradually added the chiral menthol, then added amine, stirred at room temp. for 2 h; ppt. filtered, washed (dry ethyl ether), filtrates combined, solvent removed (vac.), ppt. dissolved (toluene/hexane), stored (-20°C, 4 h), filtered, solvent removed (vac.), washed (hexane), dried (vac.); elem.anal.;
DOI:10.1016/j.molcata.2003.07.002

Reference yield:

: 69276-78-4
η5-isopropylcyclopentadienyl titanium trichloride

: 3385-94-2
hexamethyldisilathiane

: 7440-66-6
zinc

: 75-77-4
chloro-trimethyl-silane

: 111237-39-9
{(CH₃)2CHC₅H₄}4Ti₄S₄

Guidance literature:: In tetrahydrofuran; ((CH3)2CHC5H4)TiCl2(THF) prepd. in THF by the method of Lucas, C.R. and Green, M.L.H., Inorg. Synth. 16(1976)237; ((CH3)3Si)2S added to the soln.; stirring for 18 h under nitrogen; solvent removed in vac., residue extd. with hot hexane; filtrate concd. to a small volume and cooled to -25° overnight; elem. anal.;
DOI:10.1021/ja00209a023