Ethyl N-methoxy-N-methylcarbamate

Base Information

• Chemical Name: Ethyl N-methoxy-N-methylcarbamate
• CAS No.: 6919-62-6
• Molecular Formula: C5H11NO3
• Molecular Weight: 133.147
• Hs Code.: 2924199090
• European Community (EC) Number: 614-934-7
• DSSTox Substance ID: DTXSID50336427
• Wikidata: Q82103520
• Mol file: 6919-62-6.mol

Synonyms:Ethyl N-methoxy-N-methylcarbamate;Ethyl methoxy(methyl)carbamate;6919-62-6;ethylmethoxy(methyl)carbamate;Methoxy-methyl-urethan;methoxy(propyl)carbamate;N-methyl,N-methoxyurethane;N-Methyl,N-methoxy-urethane;SCHEMBL872502;Ethyl methoxy(methyl)carbamate #;DTXSID50336427;N-Carbethoxy-N-methoxymethylamine;AKOS008999607;Ethyl N-methoxy-N-methylcarbamate, 98%;A9165;FT-0751930;F1903-0372

Chemical Property of Ethyl N-methoxy-N-methylcarbamate

Chemical Property:

• Vapor Pressure: 3.48mmHg at 25°C
• Refractive Index: n20/D 1.412(lit.)
• Boiling Point: 150-155 °C(lit.)
• Flash Point: 127 °F
• PSA: 38.77000
• Density: 1.022 g/mL at 25 °C(lit.)
• LogP: 0.63610
• XLogP3: 0.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 133.07389321
• Heavy Atom Count: 9
• Complexity: 94.2

Purity/Quality:

97% ^*data from raw suppliers

Ethyl N-methoxy-N-methylcarbamate 98% ^*data from reagent suppliers

Safty Information:

• Statements: 10
• Safety Statements: 16

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCOC(=O)N(C)OC

Technology Process of Ethyl N-methoxy-N-methylcarbamate

There total 8 articles about Ethyl N-methoxy-N-methylcarbamate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

N,O-dimethylhydroxylamine*hydrochloride (6638-79-5) + chloroformic acid ethyl ester (541-41-3) → ethyl N-methoxy-N-methylcarbamate (6919-62-6)

Guidance literature:

With pyridine; dmap; In dichloromethane; at 0 - 20 ℃; for 4h;

DOI:10.1002/chem.201605011

Reference yield: 36.0%

ethyl cyanoformate (623-49-4) + N,0-dimethylhydroxylamine (1117-97-1) → ethyl N-methoxy-N-methylcarbamate (6919-62-6)

Guidance literature:

In dichloromethane; Ambient temperature;

DOI:10.1016/S0040-4020(01)88224-7

Reference yield:

ethyl N-hydroxylcarbamate (589-41-3) + dimethyl sulfate (77-78-1) → ethyl N-methoxy-N-methylcarbamate (6919-62-6)

Guidance literature:

With potassium hydroxide;

upstream raw materials:

ethyl N-hydroxylcarbamate

dimethyl sulfate

Methoxy-methyl-(2,2-dimethyl-1-isopropyl-hydrazinomethyl)-amin

chloroformic acid ethyl ester

Downstream raw materials:

N,0-dimethylhydroxylamine

2,2'-dipyridyl ketone

nonanone-5

benzophenone