[Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

Base Information

Chemical Name:[Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]
CAS No.:1194043-55-4
Molecular Formula:C₁₈H₁₇Cl₂PRu
Molecular Weight:436.283
Hs Code.:

Synonyms:

Suppliers and Price of [Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

There total 1 articles about [Ru(η6-C6H6)(PPh(CCCH3)2)Cl2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 37366-09-9
dichloro(benzene)ruthenium(II) dimer

: 39997-80-3
phenylbis(1-propynyl)phosphane

: 1194043-55-4
[Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

Guidance literature:: In acetone; (Ar); std. Schlenk technique; Ru complex was added to soln. of P ligand in acetone; stirred for 1 d; evapd.; washed (hexane); dried (vac.);
DOI:10.1021/om900502a

Reference yield: 98.0%

: 26042-63-7
silver(I) hexafluorophosphate

: 1194043-55-4
[Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

: 1194043-57-6
[Ru(η6-C6H6)(PPh(CCCH3)2)(NCCH3)Cl]PF6

Guidance literature:: In dichloromethane; acetonitrile; byproducts: AgCl; (Ar); std. Schlenk technique; soln. of Ru complex in CH2Cl2 was mixed with soln. of Ag salt in MeCN; stirred in dark for 1 d; filtered through Celite; evapd.; dried (vac.);
DOI:10.1021/om900502a

Reference yield: 41.0%

: di-μ-chlorobis{(S-2-dimethylaminoethylphenyl-C1,N)palladium(II)}

: 75-09-2
dichloromethane

: 1194043-55-4
[Ru(η6-C6H6)(PPh(CCCH3)2)Cl2]

: R(Ru),S(P),S(C)-[RuCl2(η6-benzene)(PPh(CH3CC)CC(Me)C6H4CH(Me)NMe2)PdCl]*0.5CH2Cl2

: R(Ru),R(P),S(C)-[RuCl2(η6-benzene)(PPh(CH3CC)CC(Me)C6H4CH(Me)NMe2)PdCl]*0.5CH2Cl2

Guidance literature:: In dichloromethane; (Ar); using Schlenk techniques; stirring of Ru(benzene)Cl2(CCMe)2 and (PdCl(C6H4CH(Me)NMe2))2 (0.5 equiv.) in CH2Cl2 for 1 d at room temp.; removal of solvent; silica gel chromy. (acetone/CH2Cl2, 1:3); pptn. in Et2O; elem. anal.;
DOI:10.1021/om900958p