cis-PtBr₂(SbPh₃)2

Base Information

• Chemical Name: cis-PtBr₂(SbPh₃)2
• CAS No.: 55979-03-8
• Molecular Formula: C₃₆H₃₀Br₂PtSb₂
• Molecular Weight: 1061.02
• Mol file: 55979-03-8.mol

Synonyms:

Chemical Property of cis-PtBr₂(SbPh₃)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis-PtBr₂(SbPh₃)2

There total 2 articles about cis-PtBr₂(SbPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

(CH3)4N(1+)*(C6H5)2SbBr2(1-)=(CH3)4N[(C6H5)2SbBr2] (317376-64-0) + platinum(II) chloride (10025-65-7) → cis-PtBr2(SbPh3)2 (63393-45-3,55979-03-8)

Guidance literature:

In tetrahydrofuran; benzene; under dry oxygen-free N2, THF soln. of Sb-complex was added to C6H6 suspn. of PtCl2, mixt. was stirred for 2 h; solid was filtered off, mixt. was evapd. to dryness, solid was dissolvedin CHCl3-MeOH, soln. was allowed to evaporate at room temp., elem. anal .;

DOI:10.1002/1521-3749(200011)626:11<2330::AID-ZAAC2330>3.0.CO;2-2

Reference yield:

potassium tetrachloroplatinate(II) (10025-99-7) + triphenylantimony (603-36-1) + sodium bromide (7647-15-6) → Pt(triphenylstibine)2Br2 (55979-03-8,63393-45-3)

Guidance literature:

In ethanol; water; 1 h;

DOI:10.1021/ic50021a025 DOI:10.1016/S0020-1693(00)90925-3

upstream raw materials:

potassium tetrachloroplatinate(II)

triphenylantimony

sodium bromide

(CH₃)4N⁽¹⁺⁾*(C₆H₅)2SbBr₂^(1-)=(CH₃)4N[(C₆H₅)2SbBr₂]

Refernces

• 1、 Burmeister, John L.,Basolo, Fred. "Inorganic linkage isomerism of the thiocyanate ion". . p. 1587 - 1593. Retrieved 2008/10/08.