(2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate

Base Information

Chemical Name:(2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate
CAS No.:548460-92-0
Molecular Formula:C₅₅H₅₄IrN₂OP₂*F₆P
Molecular Weight:1158.18
Hs Code.:

Synonyms:

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Chemical Property of (2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate

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Technology Process of (2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate

There total 2 articles about (2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 67410-22-4
2-amino-7,8-benzoquinoline

: 548460-85-1
[iridium(I)(tri-(p-toluylphosphine)(1,5-cyclooctadiene)]PF₆

: 7732-18-5
water

: 1333-74-0
hydrogen

: 548460-92-0
(2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate

Guidance literature:: In dichloromethane; (Ar); standard Schlenk technique; soln. of Ir complex in moist CH2Cl2 was treated with H2 (1 atm) for 30 min at 0°C; hexane was added; filtered; residue was dissolved in moist CH2Cl2; aminobenzoquinoline was added; mixt. was stirred for 30 min; hexane added; pptd.; recrystd. (CH2Cl2/Et2O); elem. anal.;
DOI:10.1039/b207339k

Reference yield:

: [IrH₂(H₃NC₁₃H₇N)(P(C₆H₄CH₃)3)2]⁽¹⁺⁾*PF₆^(1-)=[IrH₂(H₃NC₁₃H₇N)(P(C₆H₄CH₃)3)2]PF₆

: 7732-18-5
water

: 548460-92-0
(2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate

Guidance literature:: In dichloromethane-d2; byproducts: H2; (Ar); standard Schlenk technique; soln. of Ir complex in CD2Cl2 was heated to room temp.;
DOI:10.1039/b207339k

Reference yield: 83.0%

: 75-09-2
dichloromethane

: 548460-92-0
(2-amino-7,8-benzoquinolinato)(aqua)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate

: 201230-82-2
carbon monoxide

: (2-amino-7,8-benzoquinolinato)(carbonyl)bis(tri(p-tolyl)phosphine)iridium(III) hexafluorophosphate*CH₂Cl₂

Guidance literature:: In dichloromethane; byproducts: H2O; (Ar); standard Schlenk technique; soln. of Ir complex in CH2Cl2 was treated with CO (1 atm) for 30 min; hexane added; pptd.; recrystd. (CH2Cl2/hexane); elem. anal.;
DOI:10.1039/b207339k