Ethyl tetrahydrofurfuryl ether

Base Information

• Chemical Name: Ethyl tetrahydrofurfuryl ether
• CAS No.: 62435-71-6
• Molecular Formula: C7H14 O2
• Molecular Weight: 130.187
• Hs Code.: 2932190090
• European Community (EC) Number: 423-630-1,623-550-9
• NSC Number: 93907
• DSSTox Substance ID: DTXSID00886169
• Nikkaji Number: J945.222B
• Mol file: 62435-71-6.mol

Synonyms:Ethyl tetrahydrofurfuryl ether;62435-71-6;2-(ethoxymethyl)oxolane;Furan, 2-(ethoxymethyl)tetrahydro-;Ethyltetrahydrofurfurylether;AI3-30797;ETE;2-(ethoxymethyl)tetrahydrofuran;NSC93907;tetrahydrofurfuryl ethyl ether;SCHEMBL1002690;Ethyl 2-tetrahydrofurfuryl ether;DTXSID00886169;MFCD00086162;NSC 93907;NSC-93907;AKOS006275715;LS-70225;Ethyl[(tetrahydrofuran)-2-ylmethyl] ether;FT-0654746;EC 423-630-1

Chemical Property of Ethyl tetrahydrofurfuryl ether

Chemical Property:

• Appearance/Colour: A colorless clear liquid.
• Vapor Pressure: 3.05mmHg at 25°C
• Boiling Point: 160.8 °C at 760 mmHg
• Flash Point: 49.3 °
• PSA: 18.46000
• Density: 0.928 g/cm³
• LogP: 1.20190
• Water Solubility.: 300g/L at 20℃
• XLogP3: 0.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 3
• Exact Mass: 130.099379685
• Heavy Atom Count: 9
• Complexity: 73.3

Purity/Quality:

99.9% ^*data from raw suppliers

ETHYL TETRAHYDROFURFURYL ETHER Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCOCC1CCCO1

Technology Process of Ethyl tetrahydrofurfuryl ether

There total 17 articles about Ethyl tetrahydrofurfuryl ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.2%

Tetrahydrofurfuryl alcohol (97-99-4) + ethyl bromide (74-96-4) → 2-(ethoxymethyl)tetrahydrofuran (62435-71-6)

Guidance literature:

With potassium hydroxide; In water; at 85 ℃; under 1500.15 Torr; Temperature; Pressure;

Reference yield: 88.0%

Tetrahydrofurfuryl alcohol (97-99-4) + ethanol (64-17-5) → 2-(ethoxymethyl)tetrahydrofuran (62435-71-6)

Guidance literature:

With SiO₂-Al₂O₃ catalyst; at -8 - 70 ℃; under 1500.15 Torr; Temperature; Pressure; Reagent/catalyst; Large scale;

Reference yield: 79.4%

Tetrahydrofurfuryl alcohol (97-99-4) + ethene (74-85-1) → 2-(ethoxymethyl)tetrahydrofuran (62435-71-6)

Guidance literature:

With sulfuric acid; at 80 ℃; for 1.5h; under 375.038 Torr; Autoclave; Inert atmosphere;

upstream raw materials:

Tetrahydrofurfuryl alcohol

ethyl bromide

2-(diethoxymethyl)furan

(2-furyl)methyl alcohol

Refernces

• 1、 Long, Yinshuang,Wang, Yun,Wu, Haihong,Xue, Teng,Wu, Peng,Guan, Yejun. "Doping Pd/SiO2 with Na+: Changing the reductive etherification of CO to furan ring hydrogenation of furfural in ethanol". . p. 25345 - 25350. Retrieved 2019/08/28.
• 2、 Wang, Yun,Cui, Qianqian,Guan, Yejun,Wu, Peng. "Facile synthesis of furfuryl ethyl ether in high yield: Via the reductive etherification of furfural in ethanol over Pd/C under mild conditions". supporting information. p. 2110 - 2117. Retrieved 2018/05/24.